Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters

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TY  - JOUR
  - Jennings, WB,Schweppe, A,Testa, LM,Zaballos-Garcia, E,Sepulveda-Arques, J
  - 2003
  - January
  - Synlett
  - Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters
  - Validated
  - ()
  - oxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS
  - 121
  - 123
  - N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations.
DA  - 2003/01
ER  - 
@article{V43338031,
   = {Jennings,  WB and Schweppe,  A and Testa,  LM and Zaballos-Garcia,  E and Sepulveda-Arques,  J },
   = {2003},
   = {January},
   = {Synlett},
   = {Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters},
   = {Validated},
   = {()},
   = {oxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS},
  pages = {121--123},
   = {{N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations.}},
  source = {IRIS}
}
AUTHORSJennings, WB,Schweppe, A,Testa, LM,Zaballos-Garcia, E,Sepulveda-Arques, J
YEAR2003
MONTHJanuary
JOURNAL_CODESynlett
TITLEApplications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDoxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS
VOLUME
ISSUE
START_PAGE121
END_PAGE123
ABSTRACTN-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations.
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