IRIS publication 43338031
Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters
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TY - JOUR - Jennings, WB,Schweppe, A,Testa, LM,Zaballos-Garcia, E,Sepulveda-Arques, J - 2003 - January - Synlett - Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters - Validated - () - oxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS - 121 - 123 - N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations. DA - 2003/01 ER -
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@article{V43338031, = {Jennings, WB and Schweppe, A and Testa, LM and Zaballos-Garcia, E and Sepulveda-Arques, J }, = {2003}, = {January}, = {Synlett}, = {Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters}, = {Validated}, = {()}, = {oxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS}, pages = {121--123}, = {{N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations.}}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Jennings, WB,Schweppe, A,Testa, LM,Zaballos-Garcia, E,Sepulveda-Arques, J | ||
YEAR | 2003 | ||
MONTH | January | ||
JOURNAL_CODE | Synlett | ||
TITLE | Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to alpha-hydroxyesters | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | oxaziridines alpha-hydroxyesters epoxidation enolate oxidation stereoselective oxidation ASYMMETRIC-SYNTHESIS ACIDS | ||
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ISSUE | |||
START_PAGE | 121 | ||
END_PAGE | 123 | ||
ABSTRACT | N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45degreesC. Esters can be oxidised to alpha-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations. | ||
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