IRIS publication 43339614
Conformation and stereodynamics of alkyl 9-anthryl sulfoxides
RIS format for Endnote and similar
TY - JOUR - Jennings, WB,Kochanewycz, MJ,Lunazzi, L - 1997 - November - Rna-A Publication of The Rna Society - Conformation and stereodynamics of alkyl 9-anthryl sulfoxides - Validated - () - ARYL - 2271 - 2273 - Several alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations. DA - 1997/11 ER -
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@article{V43339614, = {Jennings, WB and Kochanewycz, MJ and Lunazzi, L }, = {1997}, = {November}, = {Rna-A Publication of The Rna Society}, = {Conformation and stereodynamics of alkyl 9-anthryl sulfoxides}, = {Validated}, = {()}, = {ARYL}, pages = {2271--2273}, = {{Several alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations.}}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Jennings, WB,Kochanewycz, MJ,Lunazzi, L | ||
YEAR | 1997 | ||
MONTH | November | ||
JOURNAL_CODE | Rna-A Publication of The Rna Society | ||
TITLE | Conformation and stereodynamics of alkyl 9-anthryl sulfoxides | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | ARYL | ||
VOLUME | |||
ISSUE | |||
START_PAGE | 2271 | ||
END_PAGE | 2273 | ||
ABSTRACT | Several alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations. | ||
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