Conformation and stereodynamics of alkyl 9-anthryl sulfoxides

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TY  - JOUR
  - Jennings, WB,Kochanewycz, MJ,Lunazzi, L
  - 1997
  - November
  - Rna-A Publication of The Rna Society
  - Conformation and stereodynamics of alkyl 9-anthryl sulfoxides
  - Validated
  - ()
  - ARYL
  - 2271
  - 2273
  - Several alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations.
DA  - 1997/11
ER  - 
@article{V43339614,
   = {Jennings,  WB and Kochanewycz,  MJ and Lunazzi,  L },
   = {1997},
   = {November},
   = {Rna-A Publication of The Rna Society},
   = {Conformation and stereodynamics of alkyl 9-anthryl sulfoxides},
   = {Validated},
   = {()},
   = {ARYL},
  pages = {2271--2273},
   = {{Several alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations.}},
  source = {IRIS}
}
AUTHORSJennings, WB,Kochanewycz, MJ,Lunazzi, L
YEAR1997
MONTHNovember
JOURNAL_CODERna-A Publication of The Rna Society
TITLEConformation and stereodynamics of alkyl 9-anthryl sulfoxides
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDARYL
VOLUME
ISSUE
START_PAGE2271
END_PAGE2273
ABSTRACTSeveral alkyl 9-anthryl sulfoxides exhibit broadening of the aromatic peri-proton signal in H-1 NMR spectra recorded at ambient temperature due to hindered rotation about the 9-anthryl-sulfur bond; the rotational barriers lie in the range 10.9-18.9 kcal mol(-1). The preferred conformation and torsional barriers in these sulfoxides and in mesityl methyl sulfoxide have also been investigated by molecular mechanics calculations.
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