Nitrogen-doped carbon nanotubes: growth, mechanism and structure

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TY  - JOUR
  - O'Byrne, J. P.; Li, Z.; Jones, S. L. T.; Fleming, P. G.; Larsson, J. A.; Morris. M. A.; Holmes, J. D.
  - 2011
  - November
  - Chemphyschem
  - Nitrogen-doped carbon nanotubes: growth, mechanism and structure
  - Published
  - ()
  - 12
  - 2995
  - 3001
  - Nitrogen-doped bamboo-structured carbon nanotubes have been successfully grown using a series of cobalt/molybdenum catalysts. The morphology and structure of the nanotubes were analysed by transmission electron microscopy and Raman spectroscopy. The level of nitrogen doping, as determine by X-ray photoelectron spectroscopy, was found to range between 0.5 to 2.5 at. %. The growth of bamboo-structured nanotubes in the presence of nitrogen, in preference to single-walled and multi-walled nanotubes, was due to the greater binding energy of nitrogen for cobalt in the catalyst compared to the binding strength of carbon to cobalt, as determined by density functional theory.
  - http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1439-7641
DA  - 2011/11
ER  - 
@article{V113019849,
   = {O'Byrne, J. P. and  Li, Z. and  Jones, S. L. T. and  Fleming, P. G. and  Larsson, J. A. and  Morris. M. A. and  Holmes, J. D.},
   = {2011},
   = {November},
   = {Chemphyschem},
   = {Nitrogen-doped carbon nanotubes: growth, mechanism and structure},
   = {Published},
   = {()},
   = {12},
  pages = {2995--3001},
   = {{Nitrogen-doped bamboo-structured carbon nanotubes have been successfully grown using a series of cobalt/molybdenum catalysts. The morphology and structure of the nanotubes were analysed by transmission electron microscopy and Raman spectroscopy. The level of nitrogen doping, as determine by X-ray photoelectron spectroscopy, was found to range between 0.5 to 2.5 at. %. The growth of bamboo-structured nanotubes in the presence of nitrogen, in preference to single-walled and multi-walled nanotubes, was due to the greater binding energy of nitrogen for cobalt in the catalyst compared to the binding strength of carbon to cobalt, as determined by density functional theory.}},
   = {http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1439-7641},
  source = {IRIS}
}
AUTHORSO'Byrne, J. P.; Li, Z.; Jones, S. L. T.; Fleming, P. G.; Larsson, J. A.; Morris. M. A.; Holmes, J. D.
YEAR2011
MONTHNovember
JOURNAL_CODEChemphyschem
TITLENitrogen-doped carbon nanotubes: growth, mechanism and structure
STATUSPublished
TIMES_CITED()
SEARCH_KEYWORD
VOLUME12
ISSUE
START_PAGE2995
END_PAGE3001
ABSTRACTNitrogen-doped bamboo-structured carbon nanotubes have been successfully grown using a series of cobalt/molybdenum catalysts. The morphology and structure of the nanotubes were analysed by transmission electron microscopy and Raman spectroscopy. The level of nitrogen doping, as determine by X-ray photoelectron spectroscopy, was found to range between 0.5 to 2.5 at. %. The growth of bamboo-structured nanotubes in the presence of nitrogen, in preference to single-walled and multi-walled nanotubes, was due to the greater binding energy of nitrogen for cobalt in the catalyst compared to the binding strength of carbon to cobalt, as determined by density functional theory.
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URLhttp://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1439-7641
DOI_LINK
FUNDING_BODY
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