Mechanical constraint and release generates long, ordered horizontal pores in anodic alumina templates

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TY  - JOUR
  - Bolger, C. T.; Fois, G.; Petkov, N.; Sassiat, N.; Burke, M.; Quinn, A. J.; Cross, G. L. W.; Holmes, J. D.
  - 2012
  - April
  - Nanotechnology
  - Mechanical constraint and release generates long, ordered horizontal pores in anodic alumina templates
  - Published
  - ()
  - 23
  - 175602(1)
  - 175602(10)
  - We describe the formation of long, highly ordered arrays of planar oriented anodic aluminum oxide (AAO) pores during plane parallel anodization of thin aluminum ‘finger’ microstructures fabricated on thermally oxidized silicon substrates and capped with a silicon oxide layer. The pore morphology was found to be strongly influenced by mechanical constraint imposed by the oxide layers surrounding the Al fingers. Tractions induced by the SiO2 substrate and capping layer led to frustrated volume expansion and restricted oxide flow along the interface, with extrusion of oxide into the primary pore volume, leading to the formation of dendritic pore structures and meandering pore growth. However, partial relief of the constraint by a delaminating interfacial fracture, with its tip closely following the anodization front, led to pore growth that was highly ordered with regular, hexagonally packed arrays of straight horizontal pores up to 3 um long. Detailed characterization of both straight and dendritic planar pores over a range of formation conditions using advanced microscopy techniques is reported, including volume reconstruction, enabling high quality 3D visualization of pore formation.
  - http://iopscience.iop.org/0957-4484/
DA  - 2012/04
ER  - 
@article{V137715669,
   = {Bolger, C. T. and  Fois, G. and  Petkov, N. and  Sassiat, N. and  Burke, M. and  Quinn, A. J. and  Cross, G. L. W. and  Holmes, J. D.},
   = {2012},
   = {April},
   = {Nanotechnology},
   = {Mechanical constraint and release generates long, ordered horizontal pores in anodic alumina templates},
   = {Published},
   = {()},
   = {23},
  pages = {175602(1)--175602(10)},
   = {{We describe the formation of long, highly ordered arrays of planar oriented anodic aluminum oxide (AAO) pores during plane parallel anodization of thin aluminum ‘finger’ microstructures fabricated on thermally oxidized silicon substrates and capped with a silicon oxide layer. The pore morphology was found to be strongly influenced by mechanical constraint imposed by the oxide layers surrounding the Al fingers. Tractions induced by the SiO2 substrate and capping layer led to frustrated volume expansion and restricted oxide flow along the interface, with extrusion of oxide into the primary pore volume, leading to the formation of dendritic pore structures and meandering pore growth. However, partial relief of the constraint by a delaminating interfacial fracture, with its tip closely following the anodization front, led to pore growth that was highly ordered with regular, hexagonally packed arrays of straight horizontal pores up to 3 um long. Detailed characterization of both straight and dendritic planar pores over a range of formation conditions using advanced microscopy techniques is reported, including volume reconstruction, enabling high quality 3D visualization of pore formation.}},
   = {http://iopscience.iop.org/0957-4484/},
  source = {IRIS}
}
AUTHORSBolger, C. T.; Fois, G.; Petkov, N.; Sassiat, N.; Burke, M.; Quinn, A. J.; Cross, G. L. W.; Holmes, J. D.
YEAR2012
MONTHApril
JOURNAL_CODENanotechnology
TITLEMechanical constraint and release generates long, ordered horizontal pores in anodic alumina templates
STATUSPublished
TIMES_CITED()
SEARCH_KEYWORD
VOLUME23
ISSUE
START_PAGE175602(1)
END_PAGE175602(10)
ABSTRACTWe describe the formation of long, highly ordered arrays of planar oriented anodic aluminum oxide (AAO) pores during plane parallel anodization of thin aluminum ‘finger’ microstructures fabricated on thermally oxidized silicon substrates and capped with a silicon oxide layer. The pore morphology was found to be strongly influenced by mechanical constraint imposed by the oxide layers surrounding the Al fingers. Tractions induced by the SiO2 substrate and capping layer led to frustrated volume expansion and restricted oxide flow along the interface, with extrusion of oxide into the primary pore volume, leading to the formation of dendritic pore structures and meandering pore growth. However, partial relief of the constraint by a delaminating interfacial fracture, with its tip closely following the anodization front, led to pore growth that was highly ordered with regular, hexagonally packed arrays of straight horizontal pores up to 3 um long. Detailed characterization of both straight and dendritic planar pores over a range of formation conditions using advanced microscopy techniques is reported, including volume reconstruction, enabling high quality 3D visualization of pore formation.
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URLhttp://iopscience.iop.org/0957-4484/
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