One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature

Typeset version

 

TY  - JOUR
  - Chen, L.,Xu, J.,Tanner, D. A.,Phelan, R.,Van der Meulen, M.,Holmes, J. D.,Morris, M. A.
  - 2009
  - January
  - Chemistry-A European Journal
  - One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature
  - Validated
  - ()
  - 15
  - 2
  - 440
  - 448
  - A great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6).
  - 0947-6539
  - ://000262491500018
DA  - 2009/01
ER  - 
@article{V17688930,
   = {Chen,  L. and Xu,  J. and Tanner,  D. A. and Phelan,  R. and Van der Meulen,  M. and Holmes,  J. D. and Morris,  M. A. },
   = {2009},
   = {January},
   = {Chemistry-A European Journal},
   = {One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature},
   = {Validated},
   = {()},
   = {15},
   = {2},
  pages = {440--448},
   = {{A great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6).}},
  issn = {0947-6539},
   = {://000262491500018},
  source = {IRIS}
}
AUTHORSChen, L.,Xu, J.,Tanner, D. A.,Phelan, R.,Van der Meulen, M.,Holmes, J. D.,Morris, M. A.
YEAR2009
MONTHJanuary
JOURNAL_CODEChemistry-A European Journal
TITLEOne-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME15
ISSUE2
START_PAGE440
END_PAGE448
ABSTRACTA great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6).
PUBLISHER_LOCATION
ISBN_ISSN0947-6539
EDITION
URL://000262491500018
DOI_LINK
FUNDING_BODY
GRANT_DETAILS