IRIS publication 17688930
One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature
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TY - JOUR - Chen, L.,Xu, J.,Tanner, D. A.,Phelan, R.,Van der Meulen, M.,Holmes, J. D.,Morris, M. A. - 2009 - January - Chemistry-A European Journal - One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature - Validated - () - 15 - 2 - 440 - 448 - A great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6). - 0947-6539 - ://000262491500018 DA - 2009/01 ER -
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@article{V17688930, = {Chen, L. and Xu, J. and Tanner, D. A. and Phelan, R. and Van der Meulen, M. and Holmes, J. D. and Morris, M. A. }, = {2009}, = {January}, = {Chemistry-A European Journal}, = {One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature}, = {Validated}, = {()}, = {15}, = {2}, pages = {440--448}, = {{A great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6).}}, issn = {0947-6539}, = {://000262491500018}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Chen, L.,Xu, J.,Tanner, D. A.,Phelan, R.,Van der Meulen, M.,Holmes, J. D.,Morris, M. A. | ||
YEAR | 2009 | ||
MONTH | January | ||
JOURNAL_CODE | Chemistry-A European Journal | ||
TITLE | One-Step Synthesis of Stoichiometrically Defined Metal Oxide Nanoparticles at Room Temperature | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | |||
VOLUME | 15 | ||
ISSUE | 2 | ||
START_PAGE | 440 | ||
END_PAGE | 448 | ||
ABSTRACT | A great variety of metal oxide nanoparticles have been readily synthesized by using alkali metal oxides, M2O (M is Na or Li) and soluble metal salts (metal chlorides) in polar organic Solutions, for example, methanol and ethanol, at room temperature. The oxidation states of the metals in the resulting metal oxides (Cu2O, CuO, ZnO, Al2O3, Fe2O3, Bi2O3, TiO2, SnO2, CeO2, Nb2O5, WO3 and CoFe2O4) range from 1 to 6 and remain invariable through the reactions where good control of stoichiometry is achieved. Metal oxide nanoparticles are 1-30 nm and have good monodispersivity and displayed comparable optical spectra. These syntheses are based on a general ion reaction pathway during which the precipitate Occurs when O2- ions meet metal cations (Mn+) in anhydrous Solution and the reaction equation is Mn+ + n/2 O2- --> MOn/2 (n = 1-6). | ||
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ISBN_ISSN | 0947-6539 | ||
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URL | ://000262491500018 | ||
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