Development of chemically engineered porous metal oxides for phosphate removal

Typeset version

 

TY  - JOUR
  - Delaney, P.; McManamon, C.; Hanrahan, J. P.; Copley, M. P.; Holmes, J. D.; Morris, M. A.
  - 2011
  - January
  - Journal of Hazardous Materials
  - Development of chemically engineered porous metal oxides for phosphate removal
  - Published
  - ()
  - 185
  - 382
  - 391
  - In this study, the application of ordered mesoporous silica (OMS) doped with various metal oxides (Zr, Ti, Fe and Al) were studied for the removal of (ortho) phosphate ions from water by adsorption. The materials were characterized by means of N2 physisorption (BET), powder X-ray diffraction (PXRD) and transmission electron microscopy (TEM). The doped materials had surface areas between 600 and 700m2 g−1 and exhibited pore sizes of 44¿64 A˚ . Phosphate adsorption was determined by measurement of the aqueous concentration of orthophosphate using ultraviolet¿isible (UV¿is) spectroscopy before and after extraction. The effects of different metal oxide loading ratios, initial concentration of phosphate solution, temperature and pH effects on the efficiency of phosphate removal were investigated. The doped mesoporous materials were effective adsorbents of orthophosphate and up to 100% removal was observed under appropriate conditions. `ack extracting¿the phosphate from the doped silica (following water treatment) was also investigated and shown to have little adverse effect on the adsorbent.
  - http://www.elsevier.com/wps/find/journaldescription.cws_home/502691/description#description
DA  - 2011/01
ER  - 
@article{V67658041,
   = {Delaney, P. and  McManamon, C. and  Hanrahan, J. P. and  Copley, M. P. and  Holmes, J. D. and  Morris, M. A.},
   = {2011},
   = {January},
   = {Journal of Hazardous Materials},
   = {Development of chemically engineered porous metal oxides for phosphate removal},
   = {Published},
   = {()},
   = {185},
  pages = {382--391},
   = {{In this study, the application of ordered mesoporous silica (OMS) doped with various metal oxides (Zr, Ti, Fe and Al) were studied for the removal of (ortho) phosphate ions from water by adsorption. The materials were characterized by means of N2 physisorption (BET), powder X-ray diffraction (PXRD) and transmission electron microscopy (TEM). The doped materials had surface areas between 600 and 700m2 g−1 and exhibited pore sizes of 44¿64 A˚ . Phosphate adsorption was determined by measurement of the aqueous concentration of orthophosphate using ultraviolet¿isible (UV¿is) spectroscopy before and after extraction. The effects of different metal oxide loading ratios, initial concentration of phosphate solution, temperature and pH effects on the efficiency of phosphate removal were investigated. The doped mesoporous materials were effective adsorbents of orthophosphate and up to 100% removal was observed under appropriate conditions. `ack extracting¿the phosphate from the doped silica (following water treatment) was also investigated and shown to have little adverse effect on the adsorbent.}},
   = {http://www.elsevier.com/wps/find/journaldescription.cws_home/502691/description#description},
  source = {IRIS}
}
AUTHORSDelaney, P.; McManamon, C.; Hanrahan, J. P.; Copley, M. P.; Holmes, J. D.; Morris, M. A.
YEAR2011
MONTHJanuary
JOURNAL_CODEJournal of Hazardous Materials
TITLEDevelopment of chemically engineered porous metal oxides for phosphate removal
STATUSPublished
TIMES_CITED()
SEARCH_KEYWORD
VOLUME185
ISSUE
START_PAGE382
END_PAGE391
ABSTRACTIn this study, the application of ordered mesoporous silica (OMS) doped with various metal oxides (Zr, Ti, Fe and Al) were studied for the removal of (ortho) phosphate ions from water by adsorption. The materials were characterized by means of N2 physisorption (BET), powder X-ray diffraction (PXRD) and transmission electron microscopy (TEM). The doped materials had surface areas between 600 and 700m2 g−1 and exhibited pore sizes of 44¿64 A˚ . Phosphate adsorption was determined by measurement of the aqueous concentration of orthophosphate using ultraviolet¿isible (UV¿is) spectroscopy before and after extraction. The effects of different metal oxide loading ratios, initial concentration of phosphate solution, temperature and pH effects on the efficiency of phosphate removal were investigated. The doped mesoporous materials were effective adsorbents of orthophosphate and up to 100% removal was observed under appropriate conditions. `ack extracting¿the phosphate from the doped silica (following water treatment) was also investigated and shown to have little adverse effect on the adsorbent.
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URLhttp://www.elsevier.com/wps/find/journaldescription.cws_home/502691/description#description
DOI_LINK
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