IRIS publication 15786495
The cavity ring-down absorption spectrum of the S0->T and S0-> S1 transition of jet-cooled 4-H-1-benzopyrane-4-thione
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TY - JOUR - A. A. Ruth*, T. Fernholz, R. P. Brint and M. W. D. Mansfield - 1998 - May - Chemical Physics Letters - The cavity ring-down absorption spectrum of the S0->T and S0-> S1 transition of jet-cooled 4-H-1-benzopyrane-4-thione - Validated - () - 287 - 403 - 411 - The very sensitive cavity ring-down method has been applied to the measurement of the absorption of 4-H-1-benzo-pyrane-4-thione (BPT).in a supersonic jet in the wavelength region of the S0->S1 transition between 15800 and 16650 cm-1. The absorption energies of vibronic states corroborate previous assignments in the multi-photon excitationand S0->T1phosphorescence excitation spectra of jet-cooled BPT. The symmetry forbidden 0,0 transition, S0,0->S1,0at16522 cm-1, was found to be 7.5 times weaker than the absorption transition to the triplet origin, S0,0->T1z,0. - Elsevier - http://www.sciencedirect.com/science?_ob=MImg;_imagekey=B6TFN-3T3KBR3-10-3N;_cdi=5231;_user=77869;_pii=S0009261498001766;_orig=search;_coverDate=05%2F01%2F1998;_sk=997129996;view=c;wchp=dGLzVtz-zSkzS;md5=c4fbc36703e32e08feb962cd83458f05;ie=/sdarticle.pdf - doi:10.1016/S0009-2614(98)00176-6 DA - 1998/05 ER -
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@article{V15786495, = {A. A. Ruth*, T. Fernholz, R. P. Brint and M. W. D. Mansfield}, = {1998}, = {May}, = {Chemical Physics Letters}, = {The cavity ring-down absorption spectrum of the S0->T and S0-> S1 transition of jet-cooled 4-H-1-benzopyrane-4-thione}, = {Validated}, = {()}, = {287}, pages = {403--411}, = {{The very sensitive cavity ring-down method has been applied to the measurement of the absorption of 4-H-1-benzo-pyrane-4-thione (BPT).in a supersonic jet in the wavelength region of the S0->S1 transition between 15800 and 16650 cm-1. The absorption energies of vibronic states corroborate previous assignments in the multi-photon excitationand S0->T1phosphorescence excitation spectra of jet-cooled BPT. The symmetry forbidden 0,0 transition, S0,0->S1,0at16522 cm-1, was found to be 7.5 times weaker than the absorption transition to the triplet origin, S0,0->T1z,0.}}, = {Elsevier}, = {http://www.sciencedirect.com/science?_ob=MImg;_imagekey=B6TFN-3T3KBR3-10-3N;_cdi=5231;_user=77869;_pii=S0009261498001766;_orig=search;_coverDate=05%2F01%2F1998;_sk=997129996;view=c;wchp=dGLzVtz-zSkzS;md5=c4fbc36703e32e08feb962cd83458f05;ie=/sdarticle.pdf}, = {doi:10.1016/S0009-2614(98)00176-6}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | A. A. Ruth*, T. Fernholz, R. P. Brint and M. W. D. Mansfield | ||
YEAR | 1998 | ||
MONTH | May | ||
JOURNAL_CODE | Chemical Physics Letters | ||
TITLE | The cavity ring-down absorption spectrum of the S0->T and S0-> S1 transition of jet-cooled 4-H-1-benzopyrane-4-thione | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | |||
VOLUME | 287 | ||
ISSUE | |||
START_PAGE | 403 | ||
END_PAGE | 411 | ||
ABSTRACT | The very sensitive cavity ring-down method has been applied to the measurement of the absorption of 4-H-1-benzo-pyrane-4-thione (BPT).in a supersonic jet in the wavelength region of the S0->S1 transition between 15800 and 16650 cm-1. The absorption energies of vibronic states corroborate previous assignments in the multi-photon excitationand S0->T1phosphorescence excitation spectra of jet-cooled BPT. The symmetry forbidden 0,0 transition, S0,0->S1,0at16522 cm-1, was found to be 7.5 times weaker than the absorption transition to the triplet origin, S0,0->T1z,0. | ||
PUBLISHER_LOCATION | Elsevier | ||
ISBN_ISSN | |||
EDITION | |||
URL | http://www.sciencedirect.com/science?_ob=MImg;_imagekey=B6TFN-3T3KBR3-10-3N;_cdi=5231;_user=77869;_pii=S0009261498001766;_orig=search;_coverDate=05%2F01%2F1998;_sk=997129996;view=c;wchp=dGLzVtz-zSkzS;md5=c4fbc36703e32e08feb962cd83458f05;ie=/sdarticle.pdf | ||
DOI_LINK | doi:10.1016/S0009-2614(98)00176-6 | ||
FUNDING_BODY | |||
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