TY  - JOUR
  - Fiedler, S. E.,Hoheisel, G.,Ruth*, A. A.,Hese, A.
  - 2003
  - December
  - Chemical Physics Letters
  - Incoherent broad-band cavity-enhanced absorption spectroscopy of azulene in a supersonic jet
  - Validated
  - ()
  - 382
  - 3-43-4
  - 447
  - 453447
  - The application of incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS) to isolated jet-cooled gas-phase species is demonstrated on basis of the S-1 <-- S-0 transition of azulene in a continuous supersonic expansion. By focusing white light from a high power Xe-lamp into an optically stable resonator, which is intercepted by the supersonic seeded jet, the absorption is measured over a broad spectral range between 17 300 and 20 255 cm(-1) with a resolution of approximate to4 cm(-1). The resolution, which is due to the dispersion of transmitted light by a grating monochromator, is sufficient to monitor the highly congested vibronic structure >3000 cm(-1) above the S-1,S-0 origin of azulene. The sensitivity required for this absorption experiment compares well to that of conventional pulsed cavity ring-down measurements. (C) 2003 Published by Elsevier B.V.The application of incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS) to isolated jet-cooled gas-phase species is demonstrated on basis of the S-1 <-- S-0 transition of azulene in a continuous supersonic expansion. By focusing white light from a high power Xe-lamp into an optically stable resonator, which is intercepted by the supersonic seeded jet, the absorption is measured over a broad spectral range between 17 300 and 20 255 cm(-1) with a resolution of approximate to4 cm(-1). The resolution, which is due to the dispersion of transmitted light by a grating monochromator, is sufficient to monitor the highly congested vibronic structure >3000 cm(-1) above the S-1,S-0 origin of azulene. The sensitivity required for this absorption experiment compares well to that of conventional pulsed cavity ring-down measurements. (C) 2003 Published by Elsevier B.V.
  - 0009-26140009-2614
  - ://000186927700035 ://000186927700035
DA  - 2003/12
ER  - 

@article{V67924362,
   = {Fiedler,  S. E. and Hoheisel,  G. and Ruth*,  A. A. and Hese,  A. },
   = {2003},
   = {December},
   = {Chemical Physics Letters},
   = {Incoherent broad-band cavity-enhanced absorption spectroscopy of azulene in a supersonic jet},
   = {Validated},
   = {()},
   = {382},
   = {3-43-4},
  pages = {447--453447},
   = {{The application of incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS) to isolated jet-cooled gas-phase species is demonstrated on basis of the S-1 <-- S-0 transition of azulene in a continuous supersonic expansion. By focusing white light from a high power Xe-lamp into an optically stable resonator, which is intercepted by the supersonic seeded jet, the absorption is measured over a broad spectral range between 17 300 and 20 255 cm(-1) with a resolution of approximate to4 cm(-1). The resolution, which is due to the dispersion of transmitted light by a grating monochromator, is sufficient to monitor the highly congested vibronic structure >3000 cm(-1) above the S-1,S-0 origin of azulene. The sensitivity required for this absorption experiment compares well to that of conventional pulsed cavity ring-down measurements. (C) 2003 Published by Elsevier B.V.The application of incoherent broad-band cavity-enhanced absorption spectroscopy (IBBCEAS) to isolated jet-cooled gas-phase species is demonstrated on basis of the S-1 <-- S-0 transition of azulene in a continuous supersonic expansion. By focusing white light from a high power Xe-lamp into an optically stable resonator, which is intercepted by the supersonic seeded jet, the absorption is measured over a broad spectral range between 17 300 and 20 255 cm(-1) with a resolution of approximate to4 cm(-1). The resolution, which is due to the dispersion of transmitted light by a grating monochromator, is sufficient to monitor the highly congested vibronic structure >3000 cm(-1) above the S-1,S-0 origin of azulene. The sensitivity required for this absorption experiment compares well to that of conventional pulsed cavity ring-down measurements. (C) 2003 Published by Elsevier B.V.}},
  issn = {0009-26140009-2614},
   = {://000186927700035 ://000186927700035},
  source = {IRIS}
}