The S1 <- S0 cavity ring-down absorption spectrum of jet-cooled azulene: dependence of internal conversion on the excess energy

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TY  - JOUR
  - Ruth*, A. A.,Kim, E. K.,Hese, A.
  - 1999
  - Unknown
  - Physical Chemistry Chemical Physics
  - The S1 <- S0 cavity ring-down absorption spectrum of jet-cooled azulene: dependence of internal conversion on the excess energy
  - Validated
  - ()
  - 1
  - 22
  - 5121
  - 5128
  - The S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.The S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.
  - 1463-90761463-9076
  - ://000083622500007 ://000083622500007
DA  - 1999/NaN
ER  - 
@article{V67924392,
   = {Ruth*,  A. A. and Kim,  E. K. and Hese,  A. },
   = {1999},
   = {Unknown},
   = {Physical Chemistry Chemical Physics},
   = {The S1 <- S0 cavity ring-down absorption spectrum of jet-cooled azulene: dependence of internal conversion on the excess energy},
   = {Validated},
   = {()},
   = {1},
   = {22},
  pages = {5121--5128},
   = {{The S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.The S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.}},
  issn = {1463-90761463-9076},
   = {://000083622500007 ://000083622500007},
  source = {IRIS}
}
AUTHORSRuth*, A. A.,Kim, E. K.,Hese, A.
YEAR1999
MONTHUnknown
JOURNAL_CODEPhysical Chemistry Chemical Physics
TITLEThe S1 <- S0 cavity ring-down absorption spectrum of jet-cooled azulene: dependence of internal conversion on the excess energy
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME1
ISSUE22
START_PAGE5121
END_PAGE5128
ABSTRACTThe S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.The S-0--> S-1 cavity ring-down (CRD) absorption spectrum of jet-cooled azulene is reported in the spectral region between 14275 and 17300 cm(-1). The excess energy dependence of the fast internal conversion rate k(ic) (S1S0) was investigated in the frequency domain by evaluating the linewidths of vibronic states up to excess energies of similar to hcx2500 cm(-1). A value for the S-1,S-0 lifetime of approximate to 2.6 +/- 0.4 ps was found. New experimental evidence for a conical intersection of the S-0 and S-1 potentials at approximate to 2100 +/- 100 cm(-1) was found. The possibility of azulene being one of the carriers of the diffuse interstellar bands (DIB) is briefly discussed.
PUBLISHER_LOCATION
ISBN_ISSN1463-90761463-9076
EDITION
URL://000083622500007 ://000083622500007
DOI_LINK
FUNDING_BODY
GRANT_DETAILS