Temperature dependence of viscosity and density of cis-1,4/trans-1,3-dimethylcyclohexane and several other commonly used organic solvents

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TY  - JOUR
  - Ruth*, A. A.,Lesche, H.,Nicke, B.
  - 2003
  - Unknown
  - ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY ; CHEMICAL PHYSICS
  - Temperature dependence of viscosity and density of cis-1,4/trans-1,3-dimethylcyclohexane and several other commonly used organic solvents
  - Validated
  - ()
  - 217
  - 6
  - 707
  - 722
  - The dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.The dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.
  - 0942-93520942-9352
  - ://000183487700007 ://000183487700007
DA  - 2003/NaN
ER  - 
@article{V67924394,
   = {Ruth*,  A. A. and Lesche,  H. and Nicke,  B. },
   = {2003},
   = {Unknown},
   = {ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY ; CHEMICAL PHYSICS},
   = {Temperature dependence of viscosity and density of cis-1,4/trans-1,3-dimethylcyclohexane and several other commonly used organic solvents},
   = {Validated},
   = {()},
   = {217},
   = {6},
  pages = {707--722},
   = {{The dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.The dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.}},
  issn = {0942-93520942-9352},
   = {://000183487700007 ://000183487700007},
  source = {IRIS}
}
AUTHORSRuth*, A. A.,Lesche, H.,Nicke, B.
YEAR2003
MONTHUnknown
JOURNAL_CODEZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY ; CHEMICAL PHYSICS
TITLETemperature dependence of viscosity and density of cis-1,4/trans-1,3-dimethylcyclohexane and several other commonly used organic solvents
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME217
ISSUE6
START_PAGE707
END_PAGE722
ABSTRACTThe dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.The dynamic viscosity (eta) of the glass-forming 50:50 mixture of cis-1,4/trans-1,3-dimethylcyclohexane (ct-DMCH) was measured from 293 K down to approximate to 126 K where eta similar to 1.2 x 10(6) mPas. The viscosity measurements of several other commonly used solvents cover the range from 293 K down to approximate to148K (eta similar to 1.4 x 10(4) mPa s) for 1-propanol (1-Prop), to approximate to 118 K (eta similar to 2.5 x 10(2) mPa s) for 2-methylpentane (2-MP), to approximate to 167 K (eta similar to 10.0 mPa s) for isooctane (Isooct), to approximate to 183 K (eta similar to 2.8 mPa s) for cyclopentane (CP) and down to approximate to 98 K (eta similar to 4.6 x 10(2) mPa s) for the 30:70 mixture of cyclopentane/isopentane (CP/IP). The density (rho) of all solvents was measured correspondingly over appropriate temperature ranges. For the solvents studied here, the temperature dependence of the viscosity can be represented by a single Arrhenius term down to similar to 180 K. Over a wider temperature range down to similar to 118 K the sum of two Arrhenius terms is required, and in the low temperature regime a Vogel-Tammann-Fulcher expression is necessary to adequately describe the temperature dependence of the dynamic viscosity.
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ISBN_ISSN0942-93520942-9352
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URL://000183487700007 ://000183487700007
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