TY  - JOUR
  - Collins, SG,O'Sullivan, OCM,Kelleher, PG,Maguire, AR
  - 2013
  - January
  - Organic ; Biomolecular Chemistry
  - Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides
  - Validated
  - ()
  - C-H INSERTION METAL CARBENE TRANSFORMATIONS NUCLEAR-MAGNETIC-RESONANCE ORGANIC-SYNTHESIS DIAZOCARBONYL COMPOUNDS SULPHONYL AZIDE S-OXIDES 1,4-OXATHIAN-2-ONES DIAZOSULFOXIDES CHEMISTRY
  - 11
  - 1706
  - 1725
  - Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable alpha-diazo-beta-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic alpha-diazo-beta-oxo sulfoxides are too labile to isolate and characterize.
  - DOI 10.1039/c3ob27061k
DA  - 2013/01
ER  - 

@article{V206307675,
   = {Collins,  SG and O'Sullivan,  OCM and Kelleher,  PG and Maguire,  AR },
   = {2013},
   = {January},
   = {Organic ; Biomolecular Chemistry},
   = {Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides},
   = {Validated},
   = {()},
   = {C-H INSERTION METAL CARBENE TRANSFORMATIONS NUCLEAR-MAGNETIC-RESONANCE ORGANIC-SYNTHESIS DIAZOCARBONYL COMPOUNDS SULPHONYL AZIDE S-OXIDES 1,4-OXATHIAN-2-ONES DIAZOSULFOXIDES CHEMISTRY},
   = {11},
  pages = {1706--1725},
   = {{Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable alpha-diazo-beta-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic alpha-diazo-beta-oxo sulfoxides are too labile to isolate and characterize.}},
   = {DOI 10.1039/c3ob27061k},
  source = {IRIS}
}