TY  - JOUR
  - O'Leary, P,Maguire, AR
  - 2009
  - September
  - Arkivoc
  - Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition
  - Validated
  - ()
  - Rhodium catalysis diazoketone Diels-Alder stereoselective azulenone DIAZOMETHYL KETONES BUCHNER REACTION CARBENOIDS PRODUCTS INSERTION
  - 130
  - 151
  - Rhodium catalysed intramolecular aromatic additions of diazoketones followed by Diels-Alder cycloadditions with carbon-based dienophiles leads in a highly stereoselective manner to polycyclic frameworks containing eight stereogenic centres completely controlled by the single stereocentre present in the diazoketone precursor. These cycloadditions provide interesting mechanistic insight into a dynamic equilibrium in methoxy-substituted azulenones.
DA  - 2009/09
ER  - 

@article{V43334810,
   = {O'Leary,  P and Maguire,  AR },
   = {2009},
   = {September},
   = {Arkivoc},
   = {Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition},
   = {Validated},
   = {()},
   = {Rhodium catalysis diazoketone Diels-Alder stereoselective azulenone DIAZOMETHYL KETONES BUCHNER REACTION CARBENOIDS PRODUCTS INSERTION},
  pages = {130--151},
   = {{Rhodium catalysed intramolecular aromatic additions of diazoketones followed by Diels-Alder cycloadditions with carbon-based dienophiles leads in a highly stereoselective manner to polycyclic frameworks containing eight stereogenic centres completely controlled by the single stereocentre present in the diazoketone precursor. These cycloadditions provide interesting mechanistic insight into a dynamic equilibrium in methoxy-substituted azulenones.}},
  source = {IRIS}
}