Asymmetric Synthesis of Aryl Benzyl Sulfoxides By Vanadium-Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution In Sulfoxide Oxidation

Typeset version

 

TY  - JOUR
  - Kelly, P, Lawrence, SE, Maguire, AR
  - 2006
  - June
  - European Journal of Organic Chemistry
  - Asymmetric Synthesis of Aryl Benzyl Sulfoxides By Vanadium-Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution In Sulfoxide Oxidation
  - Validated
  - ()
  - -1
  - 19
  - 4500
  - 4509
  - Enantio selective vanadium-catalysed oxidation of aryl benzyl sulfides using Bolm's procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically > 90% ee), albeit with an associated reduction in yield. The effects of ligand, solvent and reaction conditions are discussed in detail..
  - DOI 10.1002/ejoc.200600320
DA  - 2006/06
ER  - 
@article{V729038,
   = {Kelly,  P and  Lawrence,  SE and  Maguire,  AR },
   = {2006},
   = {June},
   = {European Journal of Organic Chemistry},
   = {Asymmetric Synthesis of Aryl Benzyl Sulfoxides By Vanadium-Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution In Sulfoxide Oxidation},
   = {Validated},
   = {()},
   = {-1},
   = {19},
  pages = {4500--4509},
   = {{Enantio selective vanadium-catalysed oxidation of aryl benzyl sulfides using Bolm's procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically > 90% ee), albeit with an associated reduction in yield. The effects of ligand, solvent and reaction conditions are discussed in detail..}},
   = {DOI 10.1002/ejoc.200600320},
  source = {IRIS}
}
AUTHORSKelly, P, Lawrence, SE, Maguire, AR
YEAR2006
MONTHJune
JOURNAL_CODEEuropean Journal of Organic Chemistry
TITLEAsymmetric Synthesis of Aryl Benzyl Sulfoxides By Vanadium-Catalysed Oxidation: A Combination of Enantioselective Sulfide Oxidation and Kinetic Resolution In Sulfoxide Oxidation
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME-1
ISSUE19
START_PAGE4500
END_PAGE4509
ABSTRACTEnantio selective vanadium-catalysed oxidation of aryl benzyl sulfides using Bolm's procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically > 90% ee), albeit with an associated reduction in yield. The effects of ligand, solvent and reaction conditions are discussed in detail..
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URL
DOI_LINKDOI 10.1002/ejoc.200600320
FUNDING_BODY
GRANT_DETAILS