An air-stable, cationic metallacarborane without a charge-compensated carborane ligand

George Ferguson; Jason Pollock; Patricia A. McEneaney; Donnacha P. O'Connell; Trevor R. Spalding; John F. Gallagher; Ramón Maciás; John D. Kennedy

doi:10.1039/CC9960000679

An air-stable, cationic metallacarborane without a charge-compensated carborane ligand

George Ferguson
, Jason Pollock
, Patricia A. McEneaney
, Donnacha P. O'Connell
, Trevor R. Spalding
, John F. Gallagher
, Ramón Maciás
, John D. Kennedy

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh₂Me)₂-3,1,2-closo-RhC₂B ₉H₁₁][SbF₆] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).

Original language	English
Pages (from-to)	679-681
Number of pages	3
Journal	Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/CC9960000679
Publication status	Published - 1996

Access to Document

10.1039/CC9960000679

Cite this

@article{ba1e7ed240d442dbbd1ff11d626eb0d8,

title = "An air-stable, cationic metallacarborane without a charge-compensated carborane ligand",

abstract = "The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh2Me)2-3,1,2-closo-RhC2B 9H11][SbF6] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).",

author = "George Ferguson and Jason Pollock and McEneaney, \{Patricia A.\} and O'Connell, \{Donnacha P.\} and Spalding, \{Trevor R.\} and Gallagher, \{John F.\} and Ram{\'o}n Maci{\'a}s and Kennedy, \{John D.\}",

year = "1996",

doi = "10.1039/CC9960000679",

language = "English",

pages = "679--681",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - An air-stable, cationic metallacarborane without a charge-compensated carborane ligand

AU - Ferguson, George

AU - Pollock, Jason

AU - McEneaney, Patricia A.

AU - O'Connell, Donnacha P.

AU - Spalding, Trevor R.

AU - Gallagher, John F.

AU - Maciás, Ramón

AU - Kennedy, John D.

PY - 1996

Y1 - 1996

N2 - The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh2Me)2-3,1,2-closo-RhC2B 9H11][SbF6] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).

AB - The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh2Me)2-3,1,2-closo-RhC2B 9H11][SbF6] 1, which does not contain a 'charge-compensated' carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).

UR - https://www.scopus.com/pages/publications/0006198826

U2 - 10.1039/CC9960000679

DO - 10.1039/CC9960000679

M3 - Article

AN - SCOPUS:0006198826

SN - 1359-7345

SP - 679

EP - 681

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

An air-stable, cationic metallacarborane without a charge-compensated carborane ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this