Asymmetric 1,3-dipolar cycloadditions of acrylamides in the synthesis of bioactive heterocycles

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Abstract

The chapter focuses on biologically active heterocyclic compounds in which the key step is an asymmetric 1,3-dipolar cycloaddition with an acrylamide. The use of chiral acrylamides as dipolarophiles leads to high levels of stereocontrol, due to conformational constraint in the acrylamides. Employment of chiral tertiary acrylamides containing nitrogen heterocycles is particularly effective in controlling the stereoselectivity.

Original languageEnglish
Title of host publicationBioactive Heterocycles
Subtitle of host publicationSynthesis and Biological Evaluation
PublisherNova Science Publishers, Inc.
Pages135-156
Number of pages22
ISBN (Print)9781622576364
Publication statusPublished - Jan 2013

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