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Asymmetric synthesis in carbon-carbon bond forming reactions of α-diazoketones catalysed by homochiral rhodium(II) carboxylates

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Abstract

Partial asymmetric synthesis has been observed in intramolecular C-H insertion, aromatic cycloaddition, and cyclopropanation reactions of α-diazoketones catalysed by homochiral rhodium(II) mandelate and rhodium(II) carboxylates derived from L-proline.

Original languageEnglish
Pages (from-to)361-362
Number of pages2
JournalChemical Communications
Issue number5
DOIs
Publication statusPublished - 1990

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