Chemically Bath Deposited Sb2S3Films as Optical Phase Change Materials

  • Cornel Cobianu
  • , Marin Gheorghe
  • , Mircea Modreanu
  • , Yael Gutierrez
  • , Maria Losurdo

Research output: Chapter in Book/Report/Conference proceedingsChapterpeer-review

Abstract

This paper presents the experimental results of laser-induced phase changes in chemically bath deposited (CBD) Sb2S3 films on fused silica glass substrates. The CBD allows conformal coverage of the glass substrate with surface roughness of 21.8 nm as estimated from AFM. As deposited Sb2S3 films show an amorphous-like structure as was revealed by both green laser (λex=514 nm) Raman and FT Raman (λex=1064 nm) spectroscopy. Optical transmittance indicates that the absorption edge in Sb2S3 films is 550 nm and therefore light below this wavelength will be strongly absorbed. Above certain threshold power, 2mW, of green laser (λex=514 nm) we observe that we can trigger an amorphous to crystalline phase transition in Sb2S3 films. Following this transition, we have also observed the appearance of α-Sb2O3 and the metallic Sb in the Sb2S3 films. The changes in optical properties have been investigated by spectroscopic ellipsometry.

Original languageEnglish
Title of host publication2021 International Semiconductor Conference, CAS 2021
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages249-252
Number of pages4
ISBN (Electronic)9781665435710
DOIs
Publication statusPublished - 2021
Externally publishedYes
Event44th International Semiconductor Conference, CAS 2021 - Virtual, Online, Romania
Duration: 6 Oct 20218 Oct 2021

Publication series

NameProceedings of the International Semiconductor Conference, CAS
Volume2021-October

Conference

Conference44th International Semiconductor Conference, CAS 2021
Country/TerritoryRomania
CityVirtual, Online
Period6/10/218/10/21

Keywords

  • AFM
  • Chemical bath deposition
  • phase change material
  • Raman spectroscopy
  • Sb2S3
  • spectroscopic ellipsometry

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