Crystal landscape of primary aromatic thioamides

Kevin S. Eccles; Robin E. Morrison; Anita R. Maguire; Simon E. Lawrence

doi:10.1021/cg401891f

Crystal landscape of primary aromatic thioamides

Kevin S. Eccles
, Robin E. Morrison
, Anita R. Maguire
, Simon E. Lawrence

University College Cork

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal landscape of a series of primary aromatic thioamides is described, displaying similar characteristic intermolecular hydrogen-bonding interactions in the solid state to those observed in their widely studied amide analogues, including R₂²(8) dimers and C(4) chains. In a number of cases, high Z′ values were observed in the structures. On the basis of the observed solid-state features, the thioamide functional group, which is a strong hydrogen-bond donor and moderate acceptor, offers considerable potential as a key moiety for crystal engineering.

Original language	English
Pages (from-to)	2753-2762
Number of pages	10
Journal	Crystal Growth and Design
Volume	14
Issue number	6
DOIs	https://doi.org/10.1021/cg401891f
Publication status	Published - 4 Jun 2014

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title = "Crystal landscape of primary aromatic thioamides",

abstract = "The crystal landscape of a series of primary aromatic thioamides is described, displaying similar characteristic intermolecular hydrogen-bonding interactions in the solid state to those observed in their widely studied amide analogues, including R22(8) dimers and C(4) chains. In a number of cases, high Z′ values were observed in the structures. On the basis of the observed solid-state features, the thioamide functional group, which is a strong hydrogen-bond donor and moderate acceptor, offers considerable potential as a key moiety for crystal engineering.",

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AU - Eccles, Kevin S.

AU - Morrison, Robin E.

AU - Maguire, Anita R.

AU - Lawrence, Simon E.

PY - 2014/6/4

Y1 - 2014/6/4

N2 - The crystal landscape of a series of primary aromatic thioamides is described, displaying similar characteristic intermolecular hydrogen-bonding interactions in the solid state to those observed in their widely studied amide analogues, including R22(8) dimers and C(4) chains. In a number of cases, high Z′ values were observed in the structures. On the basis of the observed solid-state features, the thioamide functional group, which is a strong hydrogen-bond donor and moderate acceptor, offers considerable potential as a key moiety for crystal engineering.

AB - The crystal landscape of a series of primary aromatic thioamides is described, displaying similar characteristic intermolecular hydrogen-bonding interactions in the solid state to those observed in their widely studied amide analogues, including R22(8) dimers and C(4) chains. In a number of cases, high Z′ values were observed in the structures. On the basis of the observed solid-state features, the thioamide functional group, which is a strong hydrogen-bond donor and moderate acceptor, offers considerable potential as a key moiety for crystal engineering.

UR - https://www.scopus.com/pages/publications/84901917247

U2 - 10.1021/cg401891f

DO - 10.1021/cg401891f

M3 - Article

AN - SCOPUS:84901917247

SN - 1528-7483

VL - 14

SP - 2753

EP - 2762

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

Crystal landscape of primary aromatic thioamides

Abstract

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