Di-/f-hydroxo-bis(diisopropylgallium)-1,4,8,11 -tetramethyl-1,4,8,11 -tetra-azacyclotetradecane (1/1)

Neu M. Boag; Kathleen M. Coward; Anthony C. Jones; Martyn E. Pemble; J. Robin Thompson

doi:10.1107/S0108270100012816

Di-/f-hydroxo-bis(diisopropylgallium)-1,4,8,11 -tetramethyl-1,4,8,11 -tetra-azacyclotetradecane (1/1)

Neu M. Boag
, Kathleen M. Coward
, Anthony C. Jones
, Martyn E. Pemble
, J. Robin Thompson

University of Salford
University of Liverpool

Research output: Contribution to journal › Article › peer-review

Abstract

The hydrolysis product [Ga₂(C₃H₇)₄(OH)₂]C ₁₄H₃₂N₄ derived from the tetrakis(triisopropylgallium)-l,4,8,ll-tetramethyl1,4,8,11- tetraazacyclotetradecane (1/1) adduct consists of a centrosymmetric ['Pr2Ga(/z-OH)]2 unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8 ll-tetramethyl-l,4,8,ll-tetraazacyclotetradecane molecule resulting in the generation of a molecular chain through the crystal.

Original language	English
Pages (from-to)	1438-1439
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	12
DOIs	https://doi.org/10.1107/S0108270100012816
Publication status	Published - 2000

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title = "Di-/f-hydroxo-bis(diisopropylgallium)-1,4,8,11 -tetramethyl-1,4,8,11 -tetra-azacyclotetradecane (1/1)",

abstract = "The hydrolysis product [Ga2(C3H7)4(OH)2]C 14H32N4 derived from the tetrakis(triisopropylgallium)-l,4,8,ll-tetramethyl1,4,8,11- tetraazacyclotetradecane (1/1) adduct consists of a centrosymmetric ['Pr2Ga(/z-OH)]2 unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8 ll-tetramethyl-l,4,8,ll-tetraazacyclotetradecane molecule resulting in the generation of a molecular chain through the crystal.",

author = "Boag, \{Neu M.\} and Coward, \{Kathleen M.\} and Jones, \{Anthony C.\} and Pemble, \{Martyn E.\} and Thompson, \{J. Robin\}",

year = "2000",

doi = "10.1107/S0108270100012816",

language = "English",

volume = "56",

pages = "1438--1439",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Di-/f-hydroxo-bis(diisopropylgallium)-1,4,8,11 -tetramethyl-1,4,8,11 -tetra-azacyclotetradecane (1/1)

AU - Boag, Neu M.

AU - Coward, Kathleen M.

AU - Jones, Anthony C.

AU - Pemble, Martyn E.

AU - Thompson, J. Robin

PY - 2000

Y1 - 2000

N2 - The hydrolysis product [Ga2(C3H7)4(OH)2]C 14H32N4 derived from the tetrakis(triisopropylgallium)-l,4,8,ll-tetramethyl1,4,8,11- tetraazacyclotetradecane (1/1) adduct consists of a centrosymmetric ['Pr2Ga(/z-OH)]2 unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8 ll-tetramethyl-l,4,8,ll-tetraazacyclotetradecane molecule resulting in the generation of a molecular chain through the crystal.

AB - The hydrolysis product [Ga2(C3H7)4(OH)2]C 14H32N4 derived from the tetrakis(triisopropylgallium)-l,4,8,ll-tetramethyl1,4,8,11- tetraazacyclotetradecane (1/1) adduct consists of a centrosymmetric ['Pr2Ga(/z-OH)]2 unit hydrogen bonded through the hydroxyl group to a nitrogen on an adjacent centrosymmetric 1,4,8 ll-tetramethyl-l,4,8,ll-tetraazacyclotetradecane molecule resulting in the generation of a molecular chain through the crystal.

UR - https://www.scopus.com/pages/publications/0034514724

U2 - 10.1107/S0108270100012816

DO - 10.1107/S0108270100012816

M3 - Article

AN - SCOPUS:0034514724

SN - 0108-2701

VL - 56

SP - 1438

EP - 1439

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

Di-/f-hydroxo-bis(diisopropylgallium)-1,4,8,11 -tetramethyl-1,4,8,11 -tetra-azacyclotetradecane (1/1)

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