TY - JOUR
T1 - Dimethylzinc adducts with macrocyclic amines
AU - Coward, Kathleen M.
AU - Jones, Anthony C.
AU - Steiner, Alexander
AU - Bickley, Jamie F.
AU - Smith, Lesley M.
AU - Pemble, Martyn E.
PY - 2000
Y1 - 2000
N2 - The structures of dimethylzinc adducts with the macrocyclic amines 1,4,8,1 l-tetramethyl-1,4,8,11-tetraazacyclotetradecane, 1, and 1,4,7,10,13,16-hexamethyl-l,4,7,10,13,16-hexaazacyclooctadecane, 2, have been determined by X-ray diffraction analysis. The adducts each contain two dimethylzinc moieties. In 1 the dimethylzinc moiety forms a six-membered chelate ring with adjacent nitrogen atoms, in preference to the more sterically strained 5-membered ring. In 2 dimethylzinc exists in a 5-membered chelate ring configuration. Compounds 1 and 2 can be used as intermediate adducts in the adduct purification of dimethylzinc for use in the MOCVD of II-VI and III-V materials.
AB - The structures of dimethylzinc adducts with the macrocyclic amines 1,4,8,1 l-tetramethyl-1,4,8,11-tetraazacyclotetradecane, 1, and 1,4,7,10,13,16-hexamethyl-l,4,7,10,13,16-hexaazacyclooctadecane, 2, have been determined by X-ray diffraction analysis. The adducts each contain two dimethylzinc moieties. In 1 the dimethylzinc moiety forms a six-membered chelate ring with adjacent nitrogen atoms, in preference to the more sterically strained 5-membered ring. In 2 dimethylzinc exists in a 5-membered chelate ring configuration. Compounds 1 and 2 can be used as intermediate adducts in the adduct purification of dimethylzinc for use in the MOCVD of II-VI and III-V materials.
UR - https://www.scopus.com/pages/publications/0003125178
U2 - 10.1039/b006253g
DO - 10.1039/b006253g
M3 - Article
AN - SCOPUS:0003125178
SN - 1470-479X
SP - 3480
EP - 3482
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 19
ER -