First analysis of the 2ν1 + 3ν3 band of NO 2 at 7192.159 cm-1

R. Raghunandan; A. Perrin; A. A. Ruth; J. Orphal

doi:10.1016/j.jms.2013.12.007

First analysis of the 2ν₁ + 3ν₃ band of NO ₂ at 7192.159 cm^-1

R. Raghunandan
, A. Perrin
, A. A. Ruth
, J. Orphal

School of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The first investigation of the very weak 2ν₁ + 3ν₃ absorption band of nitrogen dioxide, ¹⁴N ¹⁶O₂, located at 7192.1587(1) cm^-1 was performed using Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS) in the 7080-7210 cm^-1 spectral range. The assigned 2ν₁ + 3ν₃ lines involve energy levels of the (2 0 3) vibrational state with rotational quantum numbers up to K_a = 7 and N = 47. Furthermore, due to local resonances involving energy levels from the (2,2,2)â‡

Original language	English
Pages (from-to)	4-10
Number of pages	7
Journal	Journal of Molecular Spectroscopy
Volume	297
DOIs	https://doi.org/10.1016/j.jms.2013.12.007
Publication status	Published - Mar 2014

Keywords

Coriolis resonance
Electron spin-rotation resonance
Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS)
High resolution spectroscopy
Nitrogen dioxide, NO
Overtone
Ro-vibrational spectroscopy

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10.1016/j.jms.2013.12.007

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@article{12e6f5abbf8d4e2f9e985293d3d9a3fd,

title = "First analysis of the 2ν1 + 3ν3 band of NO 2 at 7192.159 cm-1",

abstract = "The first investigation of the very weak 2ν1 + 3ν3 absorption band of nitrogen dioxide, 14N 16O2, located at 7192.1587(1) cm-1 was performed using Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS) in the 7080-7210 cm-1 spectral range. The assigned 2ν1 + 3ν3 lines involve energy levels of the (2 0 3) vibrational state with rotational quantum numbers up to Ka = 7 and N = 47. Furthermore, due to local resonances involving energy levels from the (2,2,2){\^a}‡",

keywords = "Coriolis resonance, Electron spin-rotation resonance, Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS), High resolution spectroscopy, Nitrogen dioxide, NO, Overtone, Ro-vibrational spectroscopy",

author = "R. Raghunandan and A. Perrin and Ruth, \{A. A.\} and J. Orphal",

year = "2014",

month = mar,

doi = "10.1016/j.jms.2013.12.007",

language = "English",

volume = "297",

pages = "4--10",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - First analysis of the 2ν1 + 3ν3 band of NO 2 at 7192.159 cm-1

AU - Raghunandan, R.

AU - Perrin, A.

AU - Ruth, A. A.

AU - Orphal, J.

PY - 2014/3

Y1 - 2014/3

N2 - The first investigation of the very weak 2ν1 + 3ν3 absorption band of nitrogen dioxide, 14N 16O2, located at 7192.1587(1) cm-1 was performed using Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS) in the 7080-7210 cm-1 spectral range. The assigned 2ν1 + 3ν3 lines involve energy levels of the (2 0 3) vibrational state with rotational quantum numbers up to Ka = 7 and N = 47. Furthermore, due to local resonances involving energy levels from the (2,2,2)â‡

AB - The first investigation of the very weak 2ν1 + 3ν3 absorption band of nitrogen dioxide, 14N 16O2, located at 7192.1587(1) cm-1 was performed using Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS) in the 7080-7210 cm-1 spectral range. The assigned 2ν1 + 3ν3 lines involve energy levels of the (2 0 3) vibrational state with rotational quantum numbers up to Ka = 7 and N = 47. Furthermore, due to local resonances involving energy levels from the (2,2,2)â‡

KW - Coriolis resonance

KW - Electron spin-rotation resonance

KW - Fourier-transform incoherent broadband cavity-enhanced absorption spectroscopy (FT-IBBCEAS)

KW - High resolution spectroscopy

KW - Nitrogen dioxide, NO

KW - Overtone

KW - Ro-vibrational spectroscopy

UR - https://www.scopus.com/pages/publications/84893327282

U2 - 10.1016/j.jms.2013.12.007

DO - 10.1016/j.jms.2013.12.007

M3 - Article

AN - SCOPUS:84893327282

SN - 0022-2852

VL - 297

SP - 4

EP - 10

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

ER -

First analysis of the 2ν₁ + 3ν₃ band of NO ₂ at 7192.159 cm^-1

Abstract

Keywords

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