Formation of a robust and stable film comprising ionic liquid and polyoxometalate on glassy carbon electrode modified with multiwalled carbon nanotubes: Toward sensitive and fast detection of hydrogen peroxide and iodate

A robust and stable film comprising n-octylpyridinum hexafluorophosphate ([C₈Py][PF₆]) and 1:12 phosphomolybdic acid (PMo₁₂) was prepared on glassy carbon electrodes modified with multiwall carbon nanotubes (GCE/MWCNTs) by dip-coating. The cyclic voltammograms of the GCE/MWCNTs/[C₈Py][PF₆]-PMo₁₂ showed three well-defined pairs of redox peaks due to the PMo₁₂ system. The surface coverage for the immobilized PMo₁₂ and the average values of the electron transfer rate constant for three pairs of redox peaks were evaluated. The GCE/MWCNTs/[C₈Py][PF₆]-PMo₁₂ showed great electrocatalytic activity towards the reduction of H₂O₂ and iodate. The kinetic parameters of the catalytic reduction of hydrogen peroxide and iodate at the electrode surface and analytical features of the sensor for amperometric determination of hydrogen peroxide and iodate were evaluated.