Formation of nitride clusters by the action of NO+ on [M 4H3(CO)12]- (M = Ru, Os): The synthesis and structural characterization of [Ru4(μ-H) 3(CO)11(μ4-N)] and [N(PPh3) 2][Os4(CO)12(μ4-N)]

Mary A. Collins; Brian F.G. Johnson; Jack Lewis; Julian M. Mace; Jill Morris; Mary McPartlin; William J.H. Nelson; José Puga; Paul R. Raithby

doi:10.1039/C39830000689

Formation of nitride clusters by the action of NO⁺ on [M ₄H₃(CO)₁₂]^- (M = Ru, Os): The synthesis and structural characterization of [Ru₄(μ-H) ₃(CO)₁₁(μ₄-N)] and [N(PPh₃) ₂][Os₄(CO)₁₂(μ₄-N)]

Mary A. Collins
, Brian F.G. Johnson
, Jack Lewis
, Julian M. Mace
, Jill Morris
, Mary McPartlin
, William J.H. Nelson
, José Puga
, Paul R. Raithby

School of the Human Environment

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Ru₄H₃(CO)₁₂]^- with NOBF₄ in CH₂Cl₂ gives the nitride cluster [Ru₄(μ-H)₃(CO)₁₁(μ₄-N)] as one of the products and in the analogous reaction with [Os₄H ₃(CO)₁₂]^- the mono-hydrido complex [Os ₄(μ-H)-(CO)₁₂(μ₄-N)] is obtained, which upon subsequent reaction with [N(PPh₃)₂][NO₂] gives the anion [Os₄(CO)₁₂(μ₄-N)] ^-; the structures of [Ru₄(μ-H)₃(CO) ₁₁(μ₄-N)] and [Os₄(CO)₁₂(μ ₄-N)]^- have been established by X-ray analysis.

Original language	English
Pages (from-to)	689-691
Number of pages	3
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39830000689
Publication status	Published - 1983

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Collins, M. A., Johnson, B. F. G., Lewis, J., Mace, J. M., Morris, J., McPartlin, M., Nelson, W. J. H., Puga, J., & Raithby, P. R. (1983). Formation of nitride clusters by the action of NO⁺ on [M ₄H₃(CO)₁₂]^- (M = Ru, Os): The synthesis and structural characterization of [Ru₄(μ-H) ₃(CO)₁₁(μ₄-N)] and [N(PPh₃) ₂][Os₄(CO)₁₂(μ₄-N)]. Chemical Communications, (12), 689-691. https://doi.org/10.1039/C39830000689

@article{60afd02e0948486b91b7752c17f46c26,

title = "Formation of nitride clusters by the action of NO+ on [M 4H3(CO)12]- (M = Ru, Os): The synthesis and structural characterization of [Ru4(μ-H) 3(CO)11(μ4-N)] and [N(PPh3) 2][Os4(CO)12(μ4-N)]",

abstract = "Reaction of [Ru4H3(CO)12]- with NOBF4 in CH2Cl2 gives the nitride cluster [Ru4(μ-H)3(CO)11(μ4-N)] as one of the products and in the analogous reaction with [Os4H 3(CO)12]- the mono-hydrido complex [Os 4(μ-H)-(CO)12(μ4-N)] is obtained, which upon subsequent reaction with [N(PPh3)2][NO2] gives the anion [Os4(CO)12(μ4-N)] -; the structures of [Ru4(μ-H)3(CO) 11(μ4-N)] and [Os4(CO)12(μ 4-N)]- have been established by X-ray analysis.",

author = "Collins, \{Mary A.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Mace, \{Julian M.\} and Jill Morris and Mary McPartlin and Nelson, \{William J.H.\} and Jos{\'e} Puga and Raithby, \{Paul R.\}",

year = "1983",

doi = "10.1039/C39830000689",

language = "English",

pages = "689--691",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "12",

}

Collins, MA, Johnson, BFG, Lewis, J, Mace, JM, Morris, J, McPartlin, M, Nelson, WJH, Puga, J & Raithby, PR 1983, 'Formation of nitride clusters by the action of NO⁺ on [M ₄H₃(CO)₁₂]^- (M = Ru, Os): The synthesis and structural characterization of [Ru₄(μ-H) ₃(CO)₁₁(μ₄-N)] and [N(PPh₃) ₂][Os₄(CO)₁₂(μ₄-N)]', Chemical Communications, no. 12, pp. 689-691. https://doi.org/10.1039/C39830000689

Formation of nitride clusters by the action of NO⁺ on [M ₄H₃(CO)₁₂]^- (M = Ru, Os): The synthesis and structural characterization of [Ru₄(μ-H) ₃(CO)₁₁(μ₄-N)] and [N(PPh₃) ₂][Os₄(CO)₁₂(μ₄-N)]. / Collins, Mary A.; Johnson, Brian F.G.; Lewis, Jack et al.
In: Chemical Communications, No. 12, 1983, p. 689-691.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of nitride clusters by the action of NO+ on [M 4H3(CO)12]- (M = Ru, Os)

T2 - The synthesis and structural characterization of [Ru4(μ-H) 3(CO)11(μ4-N)] and [N(PPh3) 2][Os4(CO)12(μ4-N)]

AU - Collins, Mary A.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Mace, Julian M.

AU - Morris, Jill

AU - McPartlin, Mary

AU - Nelson, William J.H.

AU - Puga, José

AU - Raithby, Paul R.

PY - 1983

Y1 - 1983

N2 - Reaction of [Ru4H3(CO)12]- with NOBF4 in CH2Cl2 gives the nitride cluster [Ru4(μ-H)3(CO)11(μ4-N)] as one of the products and in the analogous reaction with [Os4H 3(CO)12]- the mono-hydrido complex [Os 4(μ-H)-(CO)12(μ4-N)] is obtained, which upon subsequent reaction with [N(PPh3)2][NO2] gives the anion [Os4(CO)12(μ4-N)] -; the structures of [Ru4(μ-H)3(CO) 11(μ4-N)] and [Os4(CO)12(μ 4-N)]- have been established by X-ray analysis.

AB - Reaction of [Ru4H3(CO)12]- with NOBF4 in CH2Cl2 gives the nitride cluster [Ru4(μ-H)3(CO)11(μ4-N)] as one of the products and in the analogous reaction with [Os4H 3(CO)12]- the mono-hydrido complex [Os 4(μ-H)-(CO)12(μ4-N)] is obtained, which upon subsequent reaction with [N(PPh3)2][NO2] gives the anion [Os4(CO)12(μ4-N)] -; the structures of [Ru4(μ-H)3(CO) 11(μ4-N)] and [Os4(CO)12(μ 4-N)]- have been established by X-ray analysis.

UR - https://www.scopus.com/pages/publications/37049112384

U2 - 10.1039/C39830000689

DO - 10.1039/C39830000689

M3 - Article

AN - SCOPUS:37049112384

SN - 0022-4936

SP - 689

EP - 691

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Formation of nitride clusters by the action of NO⁺ on [M ₄H₃(CO)₁₂]^- (M = Ru, Os): The synthesis and structural characterization of [Ru₄(μ-H) ₃(CO)₁₁(μ₄-N)] and [N(PPh₃) ₂][Os₄(CO)₁₂(μ₄-N)]

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