Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of α-diazosulfones

Christopher J. Flynn; Curtis J. Elcoate; Simon E. Lawrence; Anita R. Maguire

doi:10.1021/ja909713a

Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of α-diazosulfones

Christopher J. Flynn
, Curtis J. Elcoate
, Simon E. Lawrence
, Anita R. Maguire

University College Cork

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Excellent enantiocontrol (up to 98% ee) is achieved in copper catalyzed C-H insertions of α-diazosulfones to form thiopyrans, with up to 60% ee in C-H insertions leading to sulfolanes.

Original language	English
Pages (from-to)	1184-1185
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	4
DOIs	https://doi.org/10.1021/ja909713a
Publication status	Published - 3 Feb 2010

Access to Document

10.1021/ja909713a

Cite this

@article{548a5b840de941cab951db29fc76bcf7,

title = "Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of α-diazosulfones",

abstract = "(Chemical Equation Presented) Excellent enantiocontrol (up to 98\% ee) is achieved in copper catalyzed C-H insertions of α-diazosulfones to form thiopyrans, with up to 60\% ee in C-H insertions leading to sulfolanes.",

author = "Flynn, \{Christopher J.\} and Elcoate, \{Curtis J.\} and Lawrence, \{Simon E.\} and Maguire, \{Anita R.\}",

year = "2010",

month = feb,

day = "3",

doi = "10.1021/ja909713a",

language = "English",

volume = "132",

pages = "1184--1185",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of α-diazosulfones

AU - Flynn, Christopher J.

AU - Elcoate, Curtis J.

AU - Lawrence, Simon E.

AU - Maguire, Anita R.

PY - 2010/2/3

Y1 - 2010/2/3

N2 - (Chemical Equation Presented) Excellent enantiocontrol (up to 98% ee) is achieved in copper catalyzed C-H insertions of α-diazosulfones to form thiopyrans, with up to 60% ee in C-H insertions leading to sulfolanes.

AB - (Chemical Equation Presented) Excellent enantiocontrol (up to 98% ee) is achieved in copper catalyzed C-H insertions of α-diazosulfones to form thiopyrans, with up to 60% ee in C-H insertions leading to sulfolanes.

UR - https://www.scopus.com/pages/publications/77950396028

U2 - 10.1021/ja909713a

DO - 10.1021/ja909713a

M3 - Article

C2 - 20050655

AN - SCOPUS:77950396028

SN - 0002-7863

VL - 132

SP - 1184

EP - 1185

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 4

ER -

Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of α-diazosulfones

Abstract

Access to Document

Other files and links

Fingerprint

Cite this