Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

Catherine N. Slattery; Leslie Ann Clarke; Shane O'Neill; Aoife Ring; Alan Ford; Anita R. Maguire

doi:10.1055/s-0031-1290598

Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

Catherine N. Slattery
, Leslie Ann Clarke
, Shane O'Neill
, Aoife Ring
, Alan Ford
, Anita R. Maguire

University College Cork

Research output: Contribution to journal › Review article › peer-review

Abstract

Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of -diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.

Original language	English
Pages (from-to)	765-767
Number of pages	3
Journal	Synlett
Volume	23
Issue number	5
DOIs	https://doi.org/10.1055/s-0031-1290598
Publication status	Published - 2012

Keywords

-Buchner reaction
bis(oxazoline) ligands
C-H insertion
copper catalysis
diazocarbonyl

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10.1055/s-0031-1290598

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title = "Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds",

abstract = "Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of -diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.",

keywords = "-Buchner reaction, bis(oxazoline) ligands, C-H insertion, copper catalysis, diazocarbonyl",

author = "Slattery, \{Catherine N.\} and Clarke, \{Leslie Ann\} and Shane O'Neill and Aoife Ring and Alan Ford and Maguire, \{Anita R.\}",

year = "2012",

doi = "10.1055/s-0031-1290598",

language = "English",

volume = "23",

pages = "765--767",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "5",

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TY - JOUR

T1 - Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

AU - Slattery, Catherine N.

AU - Clarke, Leslie Ann

AU - O'Neill, Shane

AU - Ring, Aoife

AU - Ford, Alan

AU - Maguire, Anita R.

PY - 2012

Y1 - 2012

N2 - Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of -diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.

AB - Significant enhancements in enantioselectivities and reaction efficiencies in asymmetric copper-catalysed C-H insertion and aromatic addition reactions of -diazocarbonyl compounds in the presence of various group I salts are reported. For the first time in carbenoid chemistry, evidence for the critical role of the metal cation is described.

KW - -Buchner reaction

KW - bis(oxazoline) ligands

KW - C-H insertion

KW - copper catalysis

KW - diazocarbonyl

UR - https://www.scopus.com/pages/publications/84858073699

U2 - 10.1055/s-0031-1290598

DO - 10.1055/s-0031-1290598

M3 - Review article

AN - SCOPUS:84858073699

SN - 0936-5214

VL - 23

SP - 765

EP - 767

JO - Synlett

JF - Synlett

IS - 5

ER -

Investigation of additive effects in enantioselective copper-catalysed C-H insertion and aromatic addition reactions of α-diazocarbonyl compounds

Abstract

Keywords

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