New chiral diamide ligands: synthesis and application in allylic alkylation

Lorraine Bateman; Simon W. Breeden; Patrick O'Leary

doi:10.1016/j.tetasy.2008.01.018

New chiral diamide ligands: synthesis and application in allylic alkylation

Lorraine Bateman
, Simon W. Breeden
, Patrick O'Leary

University of Galway

Research output: Contribution to journal › Article › peer-review

Abstract

A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantioselectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene.

Original language	English
Pages (from-to)	391-396
Number of pages	6
Journal	Tetrahedron Asymmetry
Volume	19
Issue number	3
DOIs	https://doi.org/10.1016/j.tetasy.2008.01.018
Publication status	Published - 19 Feb 2008
Externally published	Yes

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10.1016/j.tetasy.2008.01.018

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title = "New chiral diamide ligands: synthesis and application in allylic alkylation",

abstract = "A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantioselectivities of up to 93\% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene.",

author = "Lorraine Bateman and Breeden, \{Simon W.\} and Patrick O'Leary",

year = "2008",

month = feb,

day = "19",

doi = "10.1016/j.tetasy.2008.01.018",

language = "English",

volume = "19",

pages = "391--396",

journal = "Tetrahedron Asymmetry",

issn = "0957-4166",

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number = "3",

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T1 - New chiral diamide ligands

T2 - synthesis and application in allylic alkylation

AU - Bateman, Lorraine

AU - Breeden, Simon W.

AU - O'Leary, Patrick

PY - 2008/2/19

Y1 - 2008/2/19

N2 - A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantioselectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene.

AB - A new family of chiral diamide ligands has been designed and synthesised. These ligands have been successfully applied to an asymmetric allylic substitution reaction. A palladium complex of one of the diamide ligands achieved enantioselectivities of up to 93% in the allylic alkylation of 1,3-diphenyl-3-acetoxyprop-1-ene.

UR - https://www.scopus.com/pages/publications/39149119932

U2 - 10.1016/j.tetasy.2008.01.018

DO - 10.1016/j.tetasy.2008.01.018

M3 - Article

AN - SCOPUS:39149119932

SN - 0957-4166

VL - 19

SP - 391

EP - 396

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 3

ER -

New chiral diamide ligands: synthesis and application in allylic alkylation

Abstract

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