Novel bonding modes in metallo-dithiadiazolyl complexes: Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(μ-SNCPhNS-S,S)2(PPh3) 4]·2PhMe

Arthur J. Banister; Ian B. Gorrell; Simon E. Lawrence; Christian W. Lehmann; Iain May; Gillian Tate; Alexander J. Blake; Jeremy M. Rawson

doi:10.1039/C39940001779

Novel bonding modes in metallo-dithiadiazolyl complexes: Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh₃)₂]·MeCN and [Pt₃(μ-SNCPhNS-S,S)₂(PPh₃) ₄]·2PhMe

Arthur J. Banister
, Ian B. Gorrell
, Simon E. Lawrence
, Christian W. Lehmann
, Iain May
, Gillian Tate
, Alexander J. Blake
, Jeremy M. Rawson

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Pt(PPh₃)₃] with (PhCNSSN)₂ in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh₃)₂]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt ₃(μ-SNCPhNS-S,S)₂(PPh₃)₄]; the structures of both compounds are reported.

Original language	English
Pages (from-to)	1779-1780
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39940001779
Publication status	Published - 1994
Externally published	Yes

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Banister, A. J., Gorrell, I. B., Lawrence, S. E., Lehmann, C. W., May, I., Tate, G., Blake, A. J., & Rawson, J. M. (1994). Novel bonding modes in metallo-dithiadiazolyl complexes: Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh₃)₂]·MeCN and [Pt₃(μ-SNCPhNS-S,S)₂(PPh₃) ₄]·2PhMe. Chemical Communications, (15), 1779-1780. https://doi.org/10.1039/C39940001779

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title = "Novel bonding modes in metallo-dithiadiazolyl complexes: Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(μ-SNCPhNS-S,S)2(PPh3) 4]·2PhMe",

abstract = "Reaction of [Pt(PPh3)3] with (PhCNSSN)2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt 3(μ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported.",

author = "Banister, \{Arthur J.\} and Gorrell, \{Ian B.\} and Lawrence, \{Simon E.\} and Lehmann, \{Christian W.\} and Iain May and Gillian Tate and Blake, \{Alexander J.\} and Rawson, \{Jeremy M.\}",

year = "1994",

doi = "10.1039/C39940001779",

language = "English",

pages = "1779--1780",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - Novel bonding modes in metallo-dithiadiazolyl complexes

T2 - Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh3)2]·MeCN and [Pt3(μ-SNCPhNS-S,S)2(PPh3) 4]·2PhMe

AU - Banister, Arthur J.

AU - Gorrell, Ian B.

AU - Lawrence, Simon E.

AU - Lehmann, Christian W.

AU - May, Iain

AU - Tate, Gillian

AU - Blake, Alexander J.

AU - Rawson, Jeremy M.

PY - 1994

Y1 - 1994

N2 - Reaction of [Pt(PPh3)3] with (PhCNSSN)2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt 3(μ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported.

AB - Reaction of [Pt(PPh3)3] with (PhCNSSN)2 in MeCN leads to [Pt(SNCPhNS-S-S,S)(PPh3)2]·MeCN, which decomposes in toluene to give a novel trimetallic species, [Pt 3(μ-SNCPhNS-S,S)2(PPh3)4]; the structures of both compounds are reported.

UR - https://www.scopus.com/pages/publications/37049082413

U2 - 10.1039/C39940001779

DO - 10.1039/C39940001779

M3 - Article

AN - SCOPUS:37049082413

SN - 0022-4936

SP - 1779

EP - 1780

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Novel bonding modes in metallo-dithiadiazolyl complexes: Preparation and crystal structures of [Pt(SNCPhNS-S,S)(PPh₃)₂]·MeCN and [Pt₃(μ-SNCPhNS-S,S)₂(PPh₃) ₄]·2PhMe

Abstract

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