Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins

S. M. Borisov; D. B. Papkovsky; G. V. Ponomarev; A. S. DeToma; R. Saf; I. Klimant

doi:10.1016/j.jphotochem.2009.05.018

Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins

S. M. Borisov
, D. B. Papkovsky
, G. V. Ponomarev
, A. S. DeToma
, R. Saf
, I. Klimant

School of Biochemistry and Cell Biology

Research output: Contribution to journal › Article › peer-review

Abstract

Several phosphorescent platinum(II) and palladium(II) complexes of tetrapyrrole dyes are prepared in an attempt to improve the compatibility with red laser diodes. The nature of meso-substituents in benzoporphyrin macrocycle is found to affect mainly the position of the Soret band and has little influence on the Q-bands. In rigid polymeric matrices these dyes possess more favourable photochemical properties than corresponding meso-tetraphenyltetrabenzoporphyrins. Platinum(II) chlorins show good compatibility with 635 nm laser diode and 632.8 line of He-Ne laser, and have moderate brightness with emission yields ∼2%. Photophysical properties and photostability of these dyes is assessed and compared with the known NIR-emitting oxygen indicators.

Original language	English
Pages (from-to)	87-92
Number of pages	6
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	206
Issue number	1
DOIs	https://doi.org/10.1016/j.jphotochem.2009.05.018
Publication status	Published - 5 Jul 2009

Keywords

Benzoporphyrin
Chlorin
Metal complex
Oxygen sensor
Phosphorescence

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10.1016/j.jphotochem.2009.05.018

Cite this

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title = "Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins",

abstract = "Several phosphorescent platinum(II) and palladium(II) complexes of tetrapyrrole dyes are prepared in an attempt to improve the compatibility with red laser diodes. The nature of meso-substituents in benzoporphyrin macrocycle is found to affect mainly the position of the Soret band and has little influence on the Q-bands. In rigid polymeric matrices these dyes possess more favourable photochemical properties than corresponding meso-tetraphenyltetrabenzoporphyrins. Platinum(II) chlorins show good compatibility with 635 nm laser diode and 632.8 line of He-Ne laser, and have moderate brightness with emission yields ∼2\%. Photophysical properties and photostability of these dyes is assessed and compared with the known NIR-emitting oxygen indicators.",

keywords = "Benzoporphyrin, Chlorin, Metal complex, Oxygen sensor, Phosphorescence",

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year = "2009",

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doi = "10.1016/j.jphotochem.2009.05.018",

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T1 - Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins

AU - Borisov, S. M.

AU - Papkovsky, D. B.

AU - Ponomarev, G. V.

AU - DeToma, A. S.

AU - Saf, R.

AU - Klimant, I.

PY - 2009/7/5

Y1 - 2009/7/5

N2 - Several phosphorescent platinum(II) and palladium(II) complexes of tetrapyrrole dyes are prepared in an attempt to improve the compatibility with red laser diodes. The nature of meso-substituents in benzoporphyrin macrocycle is found to affect mainly the position of the Soret band and has little influence on the Q-bands. In rigid polymeric matrices these dyes possess more favourable photochemical properties than corresponding meso-tetraphenyltetrabenzoporphyrins. Platinum(II) chlorins show good compatibility with 635 nm laser diode and 632.8 line of He-Ne laser, and have moderate brightness with emission yields ∼2%. Photophysical properties and photostability of these dyes is assessed and compared with the known NIR-emitting oxygen indicators.

AB - Several phosphorescent platinum(II) and palladium(II) complexes of tetrapyrrole dyes are prepared in an attempt to improve the compatibility with red laser diodes. The nature of meso-substituents in benzoporphyrin macrocycle is found to affect mainly the position of the Soret band and has little influence on the Q-bands. In rigid polymeric matrices these dyes possess more favourable photochemical properties than corresponding meso-tetraphenyltetrabenzoporphyrins. Platinum(II) chlorins show good compatibility with 635 nm laser diode and 632.8 line of He-Ne laser, and have moderate brightness with emission yields ∼2%. Photophysical properties and photostability of these dyes is assessed and compared with the known NIR-emitting oxygen indicators.

KW - Benzoporphyrin

KW - Chlorin

KW - Metal complex

KW - Oxygen sensor

KW - Phosphorescence

UR - https://www.scopus.com/pages/publications/67649340796

U2 - 10.1016/j.jphotochem.2009.05.018

DO - 10.1016/j.jphotochem.2009.05.018

M3 - Article

AN - SCOPUS:67649340796

SN - 1010-6030

VL - 206

SP - 87

EP - 92

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

IS - 1

ER -

Photophysical properties of the new phosphorescent platinum(II) and palladium(II) complexes of benzoporphyrins and chlorins

Abstract

Keywords

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