Polar-embedded and polar-endcapped stationary phases for LC

Gerard P. O'Sullivan; Norma M. Scully; Jeremy D. Glennon

doi:10.1080/00032711003653973

Polar-embedded and polar-endcapped stationary phases for LC

Gerard P. O'Sullivan
, Norma M. Scully
, Jeremy D. Glennon

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University College Cork

Research output: Contribution to journal › Article › peer-review

Abstract

Polar-embedded and polar-endcapped phases have become widespread over the past decade. When compared to classical alkylsilicas, they offer an alternative selectivity profile, increased stability in highly aqueous mobile phases, and improved peak shape for basic analytes. This mini-review summarizes current knowledge and applications of these phases, including the recent development of a series of N-methylamide embedded phases, prepared using supercritical carbon dioxide.

Original language	English
Pages (from-to)	1609-1629
Number of pages	21
Journal	Analytical Letters
Volume	43
Issue number	10-11
DOIs	https://doi.org/10.1080/00032711003653973
Publication status	Published - Jul 2010

Keywords

Liquid chromatography
Polar-embedded
Polar-endcapped
Stationary phase

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10.1080/00032711003653973

Cite this

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abstract = "Polar-embedded and polar-endcapped phases have become widespread over the past decade. When compared to classical alkylsilicas, they offer an alternative selectivity profile, increased stability in highly aqueous mobile phases, and improved peak shape for basic analytes. This mini-review summarizes current knowledge and applications of these phases, including the recent development of a series of N-methylamide embedded phases, prepared using supercritical carbon dioxide.",

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AB - Polar-embedded and polar-endcapped phases have become widespread over the past decade. When compared to classical alkylsilicas, they offer an alternative selectivity profile, increased stability in highly aqueous mobile phases, and improved peak shape for basic analytes. This mini-review summarizes current knowledge and applications of these phases, including the recent development of a series of N-methylamide embedded phases, prepared using supercritical carbon dioxide.

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KW - Polar-endcapped

KW - Stationary phase

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Polar-embedded and polar-endcapped stationary phases for LC

Abstract

Keywords

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