Rhodium catalysed decomposition of α-diazosulfoxides: Formation of α- oxo sulfines as intermediates

Anita R. Maguire; Patrick G. Kelleher; Simon E. Lawrence

doi:10.1016/S0040-4039(98)00630-3

Rhodium catalysed decomposition of α-diazosulfoxides: Formation of α- oxo sulfines as intermediates

Anita R. Maguire
, Patrick G. Kelleher
, Simon E. Lawrence

Research output: Contribution to journal › Article › peer-review

Abstract

Decomposition of α-diazosulfoxides using rhodium carboxylate or carboxamide catalysts proceeds via a Wolff type rearrangement to form α-oxo sulfine intermediates, which can be trapped as cycloadducts with dienes. In the absence of a diene trap, dimerisation of the sulfine intermediate is observed.

Original language	English
Pages (from-to)	3849-3852
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	22
DOIs	https://doi.org/10.1016/S0040-4039(98)00630-3
Publication status	Published - 28 May 1998

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title = "Rhodium catalysed decomposition of α-diazosulfoxides: Formation of α- oxo sulfines as intermediates",

abstract = "Decomposition of α-diazosulfoxides using rhodium carboxylate or carboxamide catalysts proceeds via a Wolff type rearrangement to form α-oxo sulfine intermediates, which can be trapped as cycloadducts with dienes. In the absence of a diene trap, dimerisation of the sulfine intermediate is observed.",

author = "Maguire, \{Anita R.\} and Kelleher, \{Patrick G.\} and Lawrence, \{Simon E.\}",

year = "1998",

month = may,

day = "28",

doi = "10.1016/S0040-4039(98)00630-3",

language = "English",

volume = "39",

pages = "3849--3852",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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number = "22",

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TY - JOUR

T1 - Rhodium catalysed decomposition of α-diazosulfoxides

T2 - Formation of α- oxo sulfines as intermediates

AU - Maguire, Anita R.

AU - Kelleher, Patrick G.

AU - Lawrence, Simon E.

PY - 1998/5/28

Y1 - 1998/5/28

N2 - Decomposition of α-diazosulfoxides using rhodium carboxylate or carboxamide catalysts proceeds via a Wolff type rearrangement to form α-oxo sulfine intermediates, which can be trapped as cycloadducts with dienes. In the absence of a diene trap, dimerisation of the sulfine intermediate is observed.

AB - Decomposition of α-diazosulfoxides using rhodium carboxylate or carboxamide catalysts proceeds via a Wolff type rearrangement to form α-oxo sulfine intermediates, which can be trapped as cycloadducts with dienes. In the absence of a diene trap, dimerisation of the sulfine intermediate is observed.

UR - https://www.scopus.com/pages/publications/0032575189

U2 - 10.1016/S0040-4039(98)00630-3

DO - 10.1016/S0040-4039(98)00630-3

M3 - Article

AN - SCOPUS:0032575189

SN - 0040-4039

VL - 39

SP - 3849

EP - 3852

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 22

ER -

Rhodium catalysed decomposition of α-diazosulfoxides: Formation of α- oxo sulfines as intermediates

Abstract

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