Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating: Improved rates and selectivities leading to exo-methylenecyclopentanes

Ian J.S. Fairlamb; Gerard P. McGlacken; Felix Weissberger

doi:10.1039/b513798e

Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating: Improved rates and selectivities leading to exo-methylenecyclopentanes

Ian J.S. Fairlamb
, Gerard P. McGlacken
, Felix Weissberger

University of York

Research output: Contribution to journal › Article › peer-review

Abstract

We herein report the effect of microwave dielectric heating in the Ru-catalysed cycloisomerisation of 1,6-dienes. Substantially improved reaction rates are attained for a series of 1,6-diene substrates, with equivalent or higher isomeric purity than conventional thermal heating.

Original language	English
Pages (from-to)	988-990
Number of pages	3
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b513798e
Publication status	Published - 2006
Externally published	Yes

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title = "Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating: Improved rates and selectivities leading to exo-methylenecyclopentanes",

abstract = "We herein report the effect of microwave dielectric heating in the Ru-catalysed cycloisomerisation of 1,6-dienes. Substantially improved reaction rates are attained for a series of 1,6-diene substrates, with equivalent or higher isomeric purity than conventional thermal heating.",

author = "Fairlamb, \{Ian J.S.\} and McGlacken, \{Gerard P.\} and Felix Weissberger",

year = "2006",

doi = "10.1039/b513798e",

language = "English",

pages = "988--990",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating

T2 - Improved rates and selectivities leading to exo-methylenecyclopentanes

AU - Fairlamb, Ian J.S.

AU - McGlacken, Gerard P.

AU - Weissberger, Felix

PY - 2006

Y1 - 2006

N2 - We herein report the effect of microwave dielectric heating in the Ru-catalysed cycloisomerisation of 1,6-dienes. Substantially improved reaction rates are attained for a series of 1,6-diene substrates, with equivalent or higher isomeric purity than conventional thermal heating.

AB - We herein report the effect of microwave dielectric heating in the Ru-catalysed cycloisomerisation of 1,6-dienes. Substantially improved reaction rates are attained for a series of 1,6-diene substrates, with equivalent or higher isomeric purity than conventional thermal heating.

UR - https://www.scopus.com/pages/publications/33244490030

U2 - 10.1039/b513798e

DO - 10.1039/b513798e

M3 - Article

C2 - 16491185

AN - SCOPUS:33244490030

SN - 1359-7345

SP - 988

EP - 990

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating: Improved rates and selectivities leading to exo-methylenecyclopentanes

Abstract

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