Self-Assembly of Heterosupermolecules

Lucy Cusack; S. Nagaraja Rao; John Wenger; Donald Fitzmaurice

doi:10.1021/cm9604470

Self-Assembly of Heterosupermolecules

Lucy Cusack
, S. Nagaraja Rao
, John Wenger
, Donald Fitzmaurice

University College Dublin

Research output: Contribution to journal › Article › peer-review

Abstract

TiO₂ nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N,N′-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-(N-tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by ¹H NMR and FT-IR spectroscopies.

Original language	English
Pages (from-to)	624-631
Number of pages	8
Journal	Chemistry of Materials
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/cm9604470
Publication status	Published - Feb 1997
Externally published	Yes

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title = "Self-Assembly of Heterosupermolecules",

abstract = "TiO2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N,N′-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-(N-tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by 1H NMR and FT-IR spectroscopies.",

author = "Lucy Cusack and Rao, \{S. Nagaraja\} and John Wenger and Donald Fitzmaurice",

year = "1997",

month = feb,

doi = "10.1021/cm9604470",

language = "English",

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pages = "624--631",

journal = "Chemistry of Materials",

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T1 - Self-Assembly of Heterosupermolecules

AU - Cusack, Lucy

AU - Rao, S. Nagaraja

AU - Wenger, John

AU - Fitzmaurice, Donald

PY - 1997/2

Y1 - 1997/2

N2 - TiO2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N,N′-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-(N-tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by 1H NMR and FT-IR spectroscopies.

AB - TiO2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N,N′-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-(N-tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by 1H NMR and FT-IR spectroscopies.

UR - https://www.scopus.com/pages/publications/0000626169

U2 - 10.1021/cm9604470

DO - 10.1021/cm9604470

M3 - Article

AN - SCOPUS:0000626169

SN - 0897-4756

VL - 9

SP - 624

EP - 631

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 2

ER -

Self-Assembly of Heterosupermolecules

Abstract

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