Self-reactivity of s-triazine and its radical cation: An electron/proton transfer process driven by ionizing radiation

Christopher J. Rhodes; Humphrey A. Moynihan

doi:10.1002/mrc.811

Self-reactivity of s-triazine and its radical cation: An electron/proton transfer process driven by ionizing radiation

Christopher J. Rhodes
, Humphrey A. Moynihan

Liverpool John Moores University

Research output: Contribution to journal › Article › peer-review

Abstract

Exposure of solutions of s-triazine in a trichlorofluoromethane matrix at 77 K to γ-radiation resulted in the formation of s-triazinyl radicals by deprotonation of the primary radical cations. The results indicate that neutral s-triazine molecules dissolve in an associated state in the Freon solvent.

Original language	English
Pages (from-to)	133-136
Number of pages	4
Journal	Magnetic Resonance in Chemistry
Volume	39
Issue number	3
DOIs	https://doi.org/10.1002/mrc.811
Publication status	Published - 2001
Externally published	Yes

Keywords

Electron/proton transfer
ESR
Ionizing radiation
S-triazine
S-triazinyl radicals
Self-reactivity

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10.1002/mrc.811

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title = "Self-reactivity of s-triazine and its radical cation: An electron/proton transfer process driven by ionizing radiation",

abstract = "Exposure of solutions of s-triazine in a trichlorofluoromethane matrix at 77 K to γ-radiation resulted in the formation of s-triazinyl radicals by deprotonation of the primary radical cations. The results indicate that neutral s-triazine molecules dissolve in an associated state in the Freon solvent.",

keywords = "Electron/proton transfer, ESR, Ionizing radiation, S-triazine, S-triazinyl radicals, Self-reactivity",

author = "Rhodes, \{Christopher J.\} and Moynihan, \{Humphrey A.\}",

year = "2001",

doi = "10.1002/mrc.811",

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volume = "39",

pages = "133--136",

journal = "Magnetic Resonance in Chemistry",

issn = "0749-1581",

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T1 - Self-reactivity of s-triazine and its radical cation

T2 - An electron/proton transfer process driven by ionizing radiation

AU - Rhodes, Christopher J.

AU - Moynihan, Humphrey A.

PY - 2001

Y1 - 2001

N2 - Exposure of solutions of s-triazine in a trichlorofluoromethane matrix at 77 K to γ-radiation resulted in the formation of s-triazinyl radicals by deprotonation of the primary radical cations. The results indicate that neutral s-triazine molecules dissolve in an associated state in the Freon solvent.

AB - Exposure of solutions of s-triazine in a trichlorofluoromethane matrix at 77 K to γ-radiation resulted in the formation of s-triazinyl radicals by deprotonation of the primary radical cations. The results indicate that neutral s-triazine molecules dissolve in an associated state in the Freon solvent.

KW - Electron/proton transfer

KW - ESR

KW - Ionizing radiation

KW - S-triazine

KW - S-triazinyl radicals

KW - Self-reactivity

UR - https://www.scopus.com/pages/publications/18844442548

U2 - 10.1002/mrc.811

DO - 10.1002/mrc.811

M3 - Article

AN - SCOPUS:18844442548

SN - 0749-1581

VL - 39

SP - 133

EP - 136

JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - 3

ER -

Self-reactivity of s-triazine and its radical cation: An electron/proton transfer process driven by ionizing radiation

Abstract

Keywords

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