Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye

Swagata Banerjee; Rimma T. Kuznetsova; Dmitri B. Papkovsky

doi:10.1016/j.snb.2015.02.016

Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye

Swagata Banerjee
, Rimma T. Kuznetsova
, Dmitri B. Papkovsky

School of Biochemistry and Cell Biology

Tomsk State University

Research output: Contribution to journal › Article › peer-review

Abstract

The detailed study of oxygen sensitive materials comprising diiodo-borondipyrromethene dye (I₂-BODIPY) encapsulated in hydrophobic polymers (Polysulfone, polyphenylene sulphide and fibrous polypropylene) is presented. These materials display strong absorption in the visible region and moderate room temperature phosphorescence in the near infrared region. They exhibit high sensitivity towards oxygen (τ_N2/τ_Air = 5-5.5), high photostability, no cross-sensitivity towards humidity and quick response time in dry gas (10 s) and water (25 s). The current system can be an attractive alternative to the commonly used noble and rare metal based O₂ sensors which use e.g. metalloporphyrins or Ru(II) complexes as indicators.

Original language	English
Pages (from-to)	229-234
Number of pages	6
Journal	Sensors and Actuators B: Chemical
Volume	212
DOIs	https://doi.org/10.1016/j.snb.2015.02.016
Publication status	Published - Jun 2015

Keywords

BODIPY dye
Halogenated
Optical oxygen sensors
Quenched phosphorescence detection
Solid-state phosphorescent materials

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10.1016/j.snb.2015.02.016

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title = "Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye",

abstract = "The detailed study of oxygen sensitive materials comprising diiodo-borondipyrromethene dye (I2-BODIPY) encapsulated in hydrophobic polymers (Polysulfone, polyphenylene sulphide and fibrous polypropylene) is presented. These materials display strong absorption in the visible region and moderate room temperature phosphorescence in the near infrared region. They exhibit high sensitivity towards oxygen (τN2/τAir = 5-5.5), high photostability, no cross-sensitivity towards humidity and quick response time in dry gas (10 s) and water (25 s). The current system can be an attractive alternative to the commonly used noble and rare metal based O2 sensors which use e.g. metalloporphyrins or Ru(II) complexes as indicators.",

keywords = "BODIPY dye, Halogenated, Optical oxygen sensors, Quenched phosphorescence detection, Solid-state phosphorescent materials",

author = "Swagata Banerjee and Kuznetsova, \{Rimma T.\} and Papkovsky, \{Dmitri B.\}",

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year = "2015",

month = jun,

doi = "10.1016/j.snb.2015.02.016",

language = "English",

volume = "212",

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TY - JOUR

T1 - Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye

AU - Banerjee, Swagata

AU - Kuznetsova, Rimma T.

AU - Papkovsky, Dmitri B.

PY - 2015/6

Y1 - 2015/6

N2 - The detailed study of oxygen sensitive materials comprising diiodo-borondipyrromethene dye (I2-BODIPY) encapsulated in hydrophobic polymers (Polysulfone, polyphenylene sulphide and fibrous polypropylene) is presented. These materials display strong absorption in the visible region and moderate room temperature phosphorescence in the near infrared region. They exhibit high sensitivity towards oxygen (τN2/τAir = 5-5.5), high photostability, no cross-sensitivity towards humidity and quick response time in dry gas (10 s) and water (25 s). The current system can be an attractive alternative to the commonly used noble and rare metal based O2 sensors which use e.g. metalloporphyrins or Ru(II) complexes as indicators.

AB - The detailed study of oxygen sensitive materials comprising diiodo-borondipyrromethene dye (I2-BODIPY) encapsulated in hydrophobic polymers (Polysulfone, polyphenylene sulphide and fibrous polypropylene) is presented. These materials display strong absorption in the visible region and moderate room temperature phosphorescence in the near infrared region. They exhibit high sensitivity towards oxygen (τN2/τAir = 5-5.5), high photostability, no cross-sensitivity towards humidity and quick response time in dry gas (10 s) and water (25 s). The current system can be an attractive alternative to the commonly used noble and rare metal based O2 sensors which use e.g. metalloporphyrins or Ru(II) complexes as indicators.

KW - BODIPY dye

KW - Halogenated

KW - Optical oxygen sensors

KW - Quenched phosphorescence detection

KW - Solid-state phosphorescent materials

UR - https://www.scopus.com/pages/publications/84923376423

U2 - 10.1016/j.snb.2015.02.016

DO - 10.1016/j.snb.2015.02.016

M3 - Article

AN - SCOPUS:84923376423

SN - 0925-4005

VL - 212

SP - 229

EP - 234

JO - Sensors and Actuators B: Chemical

JF - Sensors and Actuators B: Chemical

ER -

Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye

Abstract

Keywords

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