@misc{3734c37981bb4f988f5b5723a854b019,
title = "Sputtered lead scandium tantalate thin films: Crystallization behaviour during post-deposition annealing",
abstract = "Lead scandium titanate (PST) thin films were deposited by RF dual magnetron sputtering and then annealed either by vacuum furnace or combined rapid thermal annealing (RTA) and furnace anneal. The film structure was investigated by x-ray diffraction, scanning electron microscopy and transmission electron microscopy (TEM) and energy dispersive x-ray spectroscopy techniques. Lead loss was more severe using furnace annealing than the combined RTA and furnace anneal. The annealed films were characterized by the presence of voids and exhibited relaxor ferroelectric characteristics. PST perovskite crystal grains were found to co-exist with pyrochlore matrix in the furnace-only annealed films, whilst in RTA annealed films no apparent pyrochlore morphology was observed in the TEM image. Lead was found to diffuse through the bottom electrode Pt layer during the annealing. Films treated by combining RTA and furnace annealing have shown pyroelectric coefficients under field of up to 500 μC m-2 K-1, a dielectric loss of below 0.007 and merit figure for thermal detection of 2.5 × 10-5 Pa-1/2.",
author = "Z. Huang and Donohue, \{P. P.\} and Todd, \{M. A.\} and Jones, \{J. C.\} and Whatmore, \{R. W.\}",
year = "2001",
month = nov,
day = "7",
doi = "10.1088/0022-3727/34/21/304",
language = "English",
volume = "34",
series = "Journal of Physics D: Applied Physics",
publisher = "Institute of Physics",
edition = "21",
type = "Other",
}