Studies of degradation of waste poly (ethylene terephthalate) using autoclave technique

  • V. S. Zope
  • , S. Mishra
  • , V. S. Patil
  • , K. K. Agrawal
  • , J. P. Mahajan
  • , S. A. Firke

Research output: Contribution to journalArticlepeer-review

Abstract

Waste of poly (ethylene terephthalate) (PET) bottles is hydrolytic deploymerized in 0.5 l capacity high-pressure autoclave equipped with stirrer at 250°C and 16.596 kg/cm 2 with and without lead acetate catalyst. The percentage conversion of PET waste into monomer is seen at 24.61%. The average molecular weight of PET is investigated and found to be approximately 11690. The degradation of PET in water with and without catalyst is compared in this study. It is found that by using catalyst, the conversion increases by 63.14% as compared to depolymerization without catalyst. The velocity constants are recorded as 10 -3 min -1 and 10 -4 min -1 for with and without catalyst, respectively which is found to be first order with respect to PET concentration.

Original languageEnglish
Pages (from-to)44-46
Number of pages3
JournalJournal of the Institution of Engineers (India): Chemical Engineering Division
Volume84
Issue number1 SEP.
Publication statusPublished - Sep 2003
Externally publishedYes

Keywords

  • Degradation
  • Depolymerization
  • Hydrolysis and conversion
  • PET waste kinetics

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