Substrate mediated ordering in PmPV thin films

  • B. McCarthy
  • , R. Czerw
  • , A. Strevens
  • , A. P. Davey
  • , D. L. Carroll
  • , W. J. Blau

Research output: Contribution to journalArticlepeer-review

Abstract

Monolayer films of poly(m-phenylenevinylene-co-2,5-dioctoxy-p-phenylenevinylene) (PmPV) supported on highly orientated pyrolytic graphite (HOPG) have been investigated using scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS). While there are areas of the surface covered with a featureless polymer layer, we also observe large regions with surprisingly long range order. Structural models of the polymer, as well as tunneling spectra, suggest that this ordering is derived from substrate-polymer epitaxy.

Original languageEnglish
Pages (from-to)BB11.34.1-BB11.34.6
JournalMaterials Research Society Symposium - Proceedings
Volume598
Publication statusPublished - 2000
Externally publishedYes
EventElectrical, Optical, and Magnetic Properties of Organic Solid-State Materials V - Boston, MA, USA
Duration: 29 Nov 20003 Dec 2000

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