Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime

Debdulal Maity; Michael G.B. Drew; Jeffrey F. Godsell; Saibal Roy; Gurucharan Mukhopadhyay

doi:10.1007/s11243-009-9314-9

Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime

Debdulal Maity
, Michael G.B. Drew
, Jeffrey F. Godsell
, Saibal Roy
, Gurucharan Mukhopadhyay

Research output: Contribution to journal › Article › peer-review

Abstract

A mononuclear complex [CuL] (1), a binuclear complex [Cu ₂LCl₂(H₂O)] (2), a trinuclear complex [Cu ₃L₂](ClO₄)₂ (3) involving o-phenylenediamine and sal- icylaldehyde and another binuclear complex of a tridentate ligand (H₂L¹) [Cu₂L₂ ¹](CH₃COO)₂ (4) involving o-phenyl- enediamine and diacetylmonoxime have been synthesized, where H₂L = N,N'-o-phenylenebis(salicylideneimine) and H₂L¹ = 3-(2-aminophenylimino)butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral and magnetic studies. The binuclear complex (2) was characterized structurally where the two Cu(II) centers are connected via an oxygen-bridged arrangement.

Original language	English
Pages (from-to)	197-204
Number of pages	8
Journal	Transition Metal Chemistry
Volume	35
Issue number	2
DOIs	https://doi.org/10.1007/s11243-009-9314-9
Publication status	Published - Mar 2010

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@article{ce7355d98b0049098f951b9104b47875,

title = "Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime",

abstract = "A mononuclear complex [CuL] (1), a binuclear complex [Cu 2LCl2(H2O)] (2), a trinuclear complex [Cu 3L2](ClO4)2 (3) involving o-phenylenediamine and sal- icylaldehyde and another binuclear complex of a tridentate ligand (H2L1) [Cu2L2 1](CH3COO)2 (4) involving o-phenyl- enediamine and diacetylmonoxime have been synthesized, where H2L = N,N'-o-phenylenebis(salicylideneimine) and H2L1 = 3-(2-aminophenylimino)butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral and magnetic studies. The binuclear complex (2) was characterized structurally where the two Cu(II) centers are connected via an oxygen-bridged arrangement.",

author = "Debdulal Maity and Drew, \{Michael G.B.\} and Godsell, \{Jeffrey F.\} and Saibal Roy and Gurucharan Mukhopadhyay",

year = "2010",

month = mar,

doi = "10.1007/s11243-009-9314-9",

language = "English",

volume = "35",

pages = "197--204",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "2",

}

Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime. / Maity, Debdulal; Drew, Michael G.B.; Godsell, Jeffrey F. et al.
In: Transition Metal Chemistry, Vol. 35, No. 2, 03.2010, p. 197-204.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime

AU - Maity, Debdulal

AU - Drew, Michael G.B.

AU - Godsell, Jeffrey F.

AU - Roy, Saibal

AU - Mukhopadhyay, Gurucharan

PY - 2010/3

Y1 - 2010/3

N2 - A mononuclear complex [CuL] (1), a binuclear complex [Cu 2LCl2(H2O)] (2), a trinuclear complex [Cu 3L2](ClO4)2 (3) involving o-phenylenediamine and sal- icylaldehyde and another binuclear complex of a tridentate ligand (H2L1) [Cu2L2 1](CH3COO)2 (4) involving o-phenyl- enediamine and diacetylmonoxime have been synthesized, where H2L = N,N'-o-phenylenebis(salicylideneimine) and H2L1 = 3-(2-aminophenylimino)butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral and magnetic studies. The binuclear complex (2) was characterized structurally where the two Cu(II) centers are connected via an oxygen-bridged arrangement.

AB - A mononuclear complex [CuL] (1), a binuclear complex [Cu 2LCl2(H2O)] (2), a trinuclear complex [Cu 3L2](ClO4)2 (3) involving o-phenylenediamine and sal- icylaldehyde and another binuclear complex of a tridentate ligand (H2L1) [Cu2L2 1](CH3COO)2 (4) involving o-phenyl- enediamine and diacetylmonoxime have been synthesized, where H2L = N,N'-o-phenylenebis(salicylideneimine) and H2L1 = 3-(2-aminophenylimino)butan-2-one oxime. All the complexes have been characterized by elemental analyses, spectral and magnetic studies. The binuclear complex (2) was characterized structurally where the two Cu(II) centers are connected via an oxygen-bridged arrangement.

UR - https://www.scopus.com/pages/publications/77952668841

U2 - 10.1007/s11243-009-9314-9

DO - 10.1007/s11243-009-9314-9

M3 - Article

AN - SCOPUS:77952668841

SN - 0340-4285

VL - 35

SP - 197

EP - 204

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 2

ER -

Synthesis and characterization of Cu(II) complexes of tetradentate and tridentate symmetrical Schiff base ligands involving o-phenelenediamine, salicylaldehyde and diacetylmonoxime

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