Synthesis of oxygen-free trimethylindium using second generation adduct purification techniques

K. M. Coward; A. C. Jones; J. F. Bickley; A. Steiner; L. M. Smith; M. S. Ravetz; S. A. Rushworth; R. Odedra; J. S. Roberts; M. E. Pemble

doi:10.1016/S0022-0248(00)00653-9

Synthesis of oxygen-free trimethylindium using second generation adduct purification techniques

K. M. Coward
, A. C. Jones
, J. F. Bickley
, A. Steiner
, L. M. Smith
, M. S. Ravetz
, S. A. Rushworth
, R. Odedra
, J. S. Roberts
, M. E. Pemble

Research output: Contribution to journal › Article › peer-review

Abstract

Me₃In has been synthesized in a hydrocarbon solvent and has then been adduct purified using the nitrogen donor ligand 4,4′-methylenebis-(N,N′-dimethylaniline) (MBDA). The exclusion of ether from the synthesis and purification route leads to an ultra-low oxygen grade of Me₃In which allows the growth of InAlGaAs GRINSCH laser structures with high PL intensity. The crystal structures of the Me₃In[MBDA]₂ and (Me₃In)₂[MBDA] adducts are reported for the first time.

Original language	English
Pages (from-to)	81-85
Number of pages	5
Journal	Journal of Crystal Growth
Volume	221
Issue number	1-4
DOIs	https://doi.org/10.1016/S0022-0248(00)00653-9
Publication status	Published - Dec 2000

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@article{3036fc26a1c347b3b04a2340fa845126,

title = "Synthesis of oxygen-free trimethylindium using second generation adduct purification techniques",

abstract = "Me3In has been synthesized in a hydrocarbon solvent and has then been adduct purified using the nitrogen donor ligand 4,4′-methylenebis-(N,N′-dimethylaniline) (MBDA). The exclusion of ether from the synthesis and purification route leads to an ultra-low oxygen grade of Me3In which allows the growth of InAlGaAs GRINSCH laser structures with high PL intensity. The crystal structures of the Me3In[MBDA]2 and (Me3In)2[MBDA] adducts are reported for the first time.",

author = "Coward, \{K. M.\} and Jones, \{A. C.\} and Bickley, \{J. F.\} and A. Steiner and Smith, \{L. M.\} and Ravetz, \{M. S.\} and Rushworth, \{S. A.\} and R. Odedra and Roberts, \{J. S.\} and Pemble, \{M. E.\}",

year = "2000",

month = dec,

doi = "10.1016/S0022-0248(00)00653-9",

language = "English",

volume = "221",

pages = "81--85",

journal = "Journal of Crystal Growth",

issn = "0022-0248",

publisher = "Elsevier B.V.",

number = "1-4",

}

TY - JOUR

T1 - Synthesis of oxygen-free trimethylindium using second generation adduct purification techniques

AU - Coward, K. M.

AU - Jones, A. C.

AU - Bickley, J. F.

AU - Steiner, A.

AU - Smith, L. M.

AU - Ravetz, M. S.

AU - Rushworth, S. A.

AU - Odedra, R.

AU - Roberts, J. S.

AU - Pemble, M. E.

PY - 2000/12

Y1 - 2000/12

N2 - Me3In has been synthesized in a hydrocarbon solvent and has then been adduct purified using the nitrogen donor ligand 4,4′-methylenebis-(N,N′-dimethylaniline) (MBDA). The exclusion of ether from the synthesis and purification route leads to an ultra-low oxygen grade of Me3In which allows the growth of InAlGaAs GRINSCH laser structures with high PL intensity. The crystal structures of the Me3In[MBDA]2 and (Me3In)2[MBDA] adducts are reported for the first time.

AB - Me3In has been synthesized in a hydrocarbon solvent and has then been adduct purified using the nitrogen donor ligand 4,4′-methylenebis-(N,N′-dimethylaniline) (MBDA). The exclusion of ether from the synthesis and purification route leads to an ultra-low oxygen grade of Me3In which allows the growth of InAlGaAs GRINSCH laser structures with high PL intensity. The crystal structures of the Me3In[MBDA]2 and (Me3In)2[MBDA] adducts are reported for the first time.

UR - https://www.scopus.com/pages/publications/18244412513

U2 - 10.1016/S0022-0248(00)00653-9

DO - 10.1016/S0022-0248(00)00653-9

M3 - Article

AN - SCOPUS:18244412513

SN - 0022-0248

VL - 221

SP - 81

EP - 85

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

IS - 1-4

ER -

Synthesis of oxygen-free trimethylindium using second generation adduct purification techniques

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