Synthesis of symmetrically and unsymmetrically substituted S,S-dialkyl phosphonodithioates

D.J. Jones; E.M. O'Leary; T.P. O'Sullivan

doi:10.1016/j.tetlet.2017.09.065

Synthesis of symmetrically and unsymmetrically substituted S,S-dialkyl phosphonodithioates

D.J. Jones
, E.M. O'Leary
, T.P. O'Sullivan

Munster Technological University

Research output: Contribution to journal › Article › peer-review

Abstract

Herein, we report the synthesis of a range of S,S-dialkyl phosphonodithioates. Symmetrically substituted analogues were readily prepared from the corresponding phosphonic dichlorides in good to moderate yields, while unsymmetrically substituted variants were obtained by a sequential alkylation-deprotection-alkylation strategy.

Original language	Undefined/Unknown
Pages (from-to)	4212-4214
Number of pages	3
Journal	Tetrahedron Letters
Volume	58
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2017.09.065
Publication status	Published - 1 Nov 2017

Keywords

Organophosphorus chemistry
Organosulfur chemistry
Phosphonodithioates
Organic chemistry

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10.1016/j.tetlet.2017.09.065

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abstract = "Herein, we report the synthesis of a range of S,S-dialkyl phosphonodithioates. Symmetrically substituted analogues were readily prepared from the corresponding phosphonic dichlorides in good to moderate yields, while unsymmetrically substituted variants were obtained by a sequential alkylation-deprotection-alkylation strategy.",

keywords = "Organophosphorus chemistry, Organosulfur chemistry, Phosphonodithioates, Organic chemistry",

author = "D.J. Jones and E.M. O'Leary and T.P. O'Sullivan",

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AU - Jones, D.J.

AU - O'Leary, E.M.

AU - O'Sullivan, T.P.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - Herein, we report the synthesis of a range of S,S-dialkyl phosphonodithioates. Symmetrically substituted analogues were readily prepared from the corresponding phosphonic dichlorides in good to moderate yields, while unsymmetrically substituted variants were obtained by a sequential alkylation-deprotection-alkylation strategy.

AB - Herein, we report the synthesis of a range of S,S-dialkyl phosphonodithioates. Symmetrically substituted analogues were readily prepared from the corresponding phosphonic dichlorides in good to moderate yields, while unsymmetrically substituted variants were obtained by a sequential alkylation-deprotection-alkylation strategy.

KW - Organophosphorus chemistry

KW - Organosulfur chemistry

KW - Phosphonodithioates

KW - Organic chemistry

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UR - https://www.scopus.com/pages/publications/85030183516

U2 - 10.1016/j.tetlet.2017.09.065

DO - 10.1016/j.tetlet.2017.09.065

M3 - Article

SN - 0040-4039

VL - 58

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Synthesis of symmetrically and unsymmetrically substituted S,S-dialkyl phosphonodithioates

Abstract

Keywords

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