Taming hazardous chemistry in flow: the continuous processing of diazo and diazonium compounds

Benjamin J. Deadman; Stuart G. Collins; Anita R. Maguire

doi:10.1002/chem.201404348

Taming hazardous chemistry in flow: the continuous processing of diazo and diazonium compounds

Benjamin J. Deadman
, Stuart G. Collins
, Anita R. Maguire

University College Cork

Research output: Contribution to journal › Article › peer-review

Abstract

The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates at a range of scales with improved safety over traditional batch processes. In this minireview, the state of the art in the continuous flow processing of reactive diazo and diazonium species is discussed.

Original language	English
Pages (from-to)	2298-2308
Number of pages	11
Journal	Chemistry - A European Journal
Volume	21
Issue number	6
DOIs	https://doi.org/10.1002/chem.201404348
Publication status	Published - 2 Feb 2015

Keywords

Continuous processing
Diazocarbonyls
Diazomethane
Diazonium ions
Flow chemistry

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10.1002/chem.201404348

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abstract = "The synthetic utilities of the diazo and diazonium groups are matched only by their reputation for explosive decomposition. Continuous processing technology offers new opportunities to make and use these versatile intermediates at a range of scales with improved safety over traditional batch processes. In this minireview, the state of the art in the continuous flow processing of reactive diazo and diazonium species is discussed.",

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KW - Continuous processing

KW - Diazocarbonyls

KW - Diazomethane

KW - Diazonium ions

KW - Flow chemistry

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Taming hazardous chemistry in flow: the continuous processing of diazo and diazonium compounds

Abstract

Keywords

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