The cavity-enhanced absorption spectrum of NH3 in the near-infrared region between 6850 and 7000 cm-1

D. M. O'Leary; J. Orphal; A. A. Ruth; U. Heitmann; P. Chelin; C. E. Fellows

doi:10.1016/j.jqsrt.2007.12.007

The cavity-enhanced absorption spectrum of NH₃ in the near-infrared region between 6850 and 7000 cm^-1

D. M. O'Leary
, J. Orphal
, A. A. Ruth
, U. Heitmann
, P. Chelin
, C. E. Fellows

School of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

In this paper, we describe new high-resolution measurements of the absorption spectrum of ¹⁴NH₃ in the 6850-7000 cm^-1 region using cavity-enhanced absorption spectroscopy (CEAS), and Fourier-transform spectroscopy (FTS) between ∼6400 and 6900 cm^-1. The CEAS measurements were used to determine line positions, line intensities (cross-sections) and pressure-broadening parameters, the latter in three different bath gases. A total of 1117 NH₃ lines were observed. The accuracy of the line positions is about 0.001 cm^-1, and absorptions cross-sections as low as 1×10^-23 cm² molecule^-1 are reported.

Original language	English
Pages (from-to)	1004-1015
Number of pages	12
Journal	Journal of Quantitative Spectroscopy and Radiative Transfer
Volume	109
Issue number	6
DOIs	https://doi.org/10.1016/j.jqsrt.2007.12.007
Publication status	Published - Apr 2008

Access to Document

10.1016/j.jqsrt.2007.12.007

Cite this

@article{0258c0c7c01e4e5d96e17e45697b5eb7,

title = "The cavity-enhanced absorption spectrum of NH3 in the near-infrared region between 6850 and 7000 cm-1",

abstract = "In this paper, we describe new high-resolution measurements of the absorption spectrum of 14NH3 in the 6850-7000 cm-1 region using cavity-enhanced absorption spectroscopy (CEAS), and Fourier-transform spectroscopy (FTS) between ∼6400 and 6900 cm-1. The CEAS measurements were used to determine line positions, line intensities (cross-sections) and pressure-broadening parameters, the latter in three different bath gases. A total of 1117 NH3 lines were observed. The accuracy of the line positions is about 0.001 cm-1, and absorptions cross-sections as low as 1×10-23 cm2 molecule-1 are reported.",

author = "O'Leary, \{D. M.\} and J. Orphal and Ruth, \{A. A.\} and U. Heitmann and P. Chelin and Fellows, \{C. E.\}",

year = "2008",

month = apr,

doi = "10.1016/j.jqsrt.2007.12.007",

language = "English",

volume = "109",

pages = "1004--1015",

journal = "Journal of Quantitative Spectroscopy and Radiative Transfer",

issn = "0022-4073",

publisher = "Elsevier Ltd",

number = "6",

}

TY - JOUR

T1 - The cavity-enhanced absorption spectrum of NH3 in the near-infrared region between 6850 and 7000 cm-1

AU - O'Leary, D. M.

AU - Orphal, J.

AU - Ruth, A. A.

AU - Heitmann, U.

AU - Chelin, P.

AU - Fellows, C. E.

PY - 2008/4

Y1 - 2008/4

N2 - In this paper, we describe new high-resolution measurements of the absorption spectrum of 14NH3 in the 6850-7000 cm-1 region using cavity-enhanced absorption spectroscopy (CEAS), and Fourier-transform spectroscopy (FTS) between ∼6400 and 6900 cm-1. The CEAS measurements were used to determine line positions, line intensities (cross-sections) and pressure-broadening parameters, the latter in three different bath gases. A total of 1117 NH3 lines were observed. The accuracy of the line positions is about 0.001 cm-1, and absorptions cross-sections as low as 1×10-23 cm2 molecule-1 are reported.

AB - In this paper, we describe new high-resolution measurements of the absorption spectrum of 14NH3 in the 6850-7000 cm-1 region using cavity-enhanced absorption spectroscopy (CEAS), and Fourier-transform spectroscopy (FTS) between ∼6400 and 6900 cm-1. The CEAS measurements were used to determine line positions, line intensities (cross-sections) and pressure-broadening parameters, the latter in three different bath gases. A total of 1117 NH3 lines were observed. The accuracy of the line positions is about 0.001 cm-1, and absorptions cross-sections as low as 1×10-23 cm2 molecule-1 are reported.

UR - https://www.scopus.com/pages/publications/40649104981

U2 - 10.1016/j.jqsrt.2007.12.007

DO - 10.1016/j.jqsrt.2007.12.007

M3 - Article

AN - SCOPUS:40649104981

SN - 0022-4073

VL - 109

SP - 1004

EP - 1015

JO - Journal of Quantitative Spectroscopy and Radiative Transfer

JF - Journal of Quantitative Spectroscopy and Radiative Transfer

IS - 6

ER -

The cavity-enhanced absorption spectrum of NH₃ in the near-infrared region between 6850 and 7000 cm^-1

Abstract

Access to Document

Other files and links

Fingerprint

Cite this