The formation and characterisation of lanthanum oxide based Si/high-k/NiSi gate stacks by electron-beam evaporation: An examination of in-situ amorphous silicon capping and NiSi formation

  • P. K. Hurley
  • , M. Pijolat
  • , K. Cherkaoui
  • , E. O. Connor
  • , D. O'Connell
  • , M. A. Negara
  • , M. C. Lemme
  • , H. D.B. Gottlob
  • , M. Schmidt
  • , K. Stegmaier
  • , U. Schwalke
  • , S. Hall
  • , O. Buiu
  • , O. Engstrom
  • , S. B. Newcomb

Research output: Chapter in Book/Report/Conference proceedingsChapterpeer-review

Abstract

The electrical and physical properties of La2O3 based NiSi/High-k/Si structures formed by electron beam evaporation, in-situ amorphous silicon capping and ex-situ NiSi formation are presented for the (100) and (110)Si substrate orientations. The silicon substrate orientation, (100) or (110), does not affect leakage current density or the maximum accumulation capacitance, but does have an impact on interface state densities. The interface states exhibit the electrical signature of Pbo centres for the (100)Si orientation and can be annealed in a H2/N2 ambient. The samples exhibit negligible hysteresis (<2mV). No interfacial silicon layer is observed between the La based high-k film and the silicon substrate. The extracted k value for the La2O3 based thin films is m the range 11-12 suggesting silicate formation The work indicates an alternative approach for the examination of NiSi/high-k/Si MOS structures without ambient exposure of the high-k layer

Original languageEnglish
Title of host publicationECS Transactions - 5th International Symposium on High Dielectric Constant Materials and Gate Stacks
PublisherElectrochemical Society Inc.
Pages145-156
Number of pages12
Edition4
ISBN (Electronic)9781566775700
ISBN (Print)9781566775700
DOIs
Publication statusPublished - 2007
Event5th International Symposium on High Dielectric Constant Materials and Gate Stacks - 212th ECS Meeting - Washington, DC, United States
Duration: 8 Oct 200710 Oct 2007

Publication series

NameECS Transactions
Number4
Volume11
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

Conference5th International Symposium on High Dielectric Constant Materials and Gate Stacks - 212th ECS Meeting
Country/TerritoryUnited States
CityWashington, DC
Period8/10/0710/10/07

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