The preparation and X-ray crystal structure of the first metal-1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)2][AsF 6]2, a transfer agent for the dithiadiazolylium ring

Arthur J. Banister; Ian Lavender; Simon E. Lawrence; Jeremy M. Rawson; William Clegg

doi:10.1039/C39940000029

The preparation and X-ray crystal structure of the first metal-1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)₂][AsF ₆]₂, a transfer agent for the dithiadiazolylium ring

Arthur J. Banister
, Ian Lavender
, Simon E. Lawrence
, Jeremy M. Rawson
, William Clegg

Durham University
Newcastle University

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of two equivalents of [SNS][AsF₆] with Hg(CN) ₂ yields [Hg(CNSNS)₂][AsF₆]₂ 1, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(V) of [I-CNSNS]⁺ and previously unreported [Br-CNSNS]⁺, thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.

Original language	English
Pages (from-to)	29-30
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39940000029
Publication status	Published - 1994
Externally published	Yes

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title = "The preparation and X-ray crystal structure of the first metal-1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)2][AsF 6]2, a transfer agent for the dithiadiazolylium ring",

abstract = "The reaction of two equivalents of [SNS][AsF6] with Hg(CN) 2 yields [Hg(CNSNS)2][AsF6]2 1, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(V) of [I-CNSNS]+ and previously unreported [Br-CNSNS]+, thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.",

author = "Banister, \{Arthur J.\} and Ian Lavender and Lawrence, \{Simon E.\} and Rawson, \{Jeremy M.\} and William Clegg",

year = "1994",

doi = "10.1039/C39940000029",

language = "English",

pages = "29--30",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "1",

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T1 - The preparation and X-ray crystal structure of the first metal-1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)2][AsF 6]2, a transfer agent for the dithiadiazolylium ring

AU - Banister, Arthur J.

AU - Lavender, Ian

AU - Lawrence, Simon E.

AU - Rawson, Jeremy M.

AU - Clegg, William

PY - 1994

Y1 - 1994

N2 - The reaction of two equivalents of [SNS][AsF6] with Hg(CN) 2 yields [Hg(CNSNS)2][AsF6]2 1, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(V) of [I-CNSNS]+ and previously unreported [Br-CNSNS]+, thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.

AB - The reaction of two equivalents of [SNS][AsF6] with Hg(CN) 2 yields [Hg(CNSNS)2][AsF6]2 1, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(V) of [I-CNSNS]+ and previously unreported [Br-CNSNS]+, thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.

UR - https://www.scopus.com/pages/publications/37049081709

U2 - 10.1039/C39940000029

DO - 10.1039/C39940000029

M3 - Article

AN - SCOPUS:37049081709

SN - 0022-4936

SP - 29

EP - 30

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

The preparation and X-ray crystal structure of the first metal-1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)₂][AsF ₆]₂, a transfer agent for the dithiadiazolylium ring

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