The synthesis of metal organic compounds of calcium, strontium and barium by ammonia gas-saturated ethereal solvents

Simon R. Drake; David J. Otway

doi:10.1039/C39910000517

The synthesis of metal organic compounds of calcium, strontium and barium by ammonia gas-saturated ethereal solvents

Simon R. Drake
, David J. Otway

Imperial College London

Research output: Contribution to journal › Article › peer-review

Abstract

The activation of the alkaline earth metals Ca, Sr and Ba in ammonia gas-saturated ethereal solvents at room temperature leads to rapid reaction with hexamethyldisilazide, pentamethylcyclopentadiene, triphenylsilanol, phenylacetylene, and triphenylmethane to yield the corresponding silamide, metallocene, siloxide, phenylacetylide and triphenylmethyl derivatives; ESR spectroscopic studies of the reaction system have detected the presence of solvated electrons.

Original language	English
Pages (from-to)	517-519
Number of pages	3
Journal	Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C39910000517
Publication status	Published - 1991
Externally published	Yes

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title = "The synthesis of metal organic compounds of calcium, strontium and barium by ammonia gas-saturated ethereal solvents",

abstract = "The activation of the alkaline earth metals Ca, Sr and Ba in ammonia gas-saturated ethereal solvents at room temperature leads to rapid reaction with hexamethyldisilazide, pentamethylcyclopentadiene, triphenylsilanol, phenylacetylene, and triphenylmethane to yield the corresponding silamide, metallocene, siloxide, phenylacetylide and triphenylmethyl derivatives; ESR spectroscopic studies of the reaction system have detected the presence of solvated electrons.",

author = "Drake, \{Simon R.\} and Otway, \{David J.\}",

year = "1991",

doi = "10.1039/C39910000517",

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pages = "517--519",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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N2 - The activation of the alkaline earth metals Ca, Sr and Ba in ammonia gas-saturated ethereal solvents at room temperature leads to rapid reaction with hexamethyldisilazide, pentamethylcyclopentadiene, triphenylsilanol, phenylacetylene, and triphenylmethane to yield the corresponding silamide, metallocene, siloxide, phenylacetylide and triphenylmethyl derivatives; ESR spectroscopic studies of the reaction system have detected the presence of solvated electrons.

AB - The activation of the alkaline earth metals Ca, Sr and Ba in ammonia gas-saturated ethereal solvents at room temperature leads to rapid reaction with hexamethyldisilazide, pentamethylcyclopentadiene, triphenylsilanol, phenylacetylene, and triphenylmethane to yield the corresponding silamide, metallocene, siloxide, phenylacetylide and triphenylmethyl derivatives; ESR spectroscopic studies of the reaction system have detected the presence of solvated electrons.

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DO - 10.1039/C39910000517

M3 - Article

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The synthesis of metal organic compounds of calcium, strontium and barium by ammonia gas-saturated ethereal solvents

Abstract

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