The x-ray crystal structure and electronic properties of [Cu(bipy) 2(ONO)][NO3](bipy = 2,2′-bipyridyl) at 298 and 165 K, a fluxional cis-distorted octahedral CuN4O2 chromophore

Charles Simmons; Abraham Clearfield; William Fitzgerald; Suresh Tyagi; Brian Hathaway

doi:10.1039/C39830000189

The x-ray crystal structure and electronic properties of [Cu(bipy) ₂(ONO)][NO₃](bipy = 2,2′-bipyridyl) at 298 and 165 K, a fluxional cis-distorted octahedral CuN₄O₂ chromophore

Charles Simmons
, Abraham Clearfield
, William Fitzgerald
, Suresh Tyagi
, Brian Hathaway

Cork University Business School

Research output: Contribution to journal › Article › peer-review

Abstract

The X-ray crystal structures of [Cu(bipy)₂(ONO)][NO₃] (bipy = 2,2′-bipyridyl) are reported at 298 and 165 K; significant differences occur which are consistent with a fluxional behaviour of the CuN₄O₂ chromophore, and enable the underlying static stereochemistry to be predicted and rationalised using the i.r. spectrum of the nitrito-group and the electronic reflectance spectrum of the CuN ₄O₂ chromophore.

Original language	English
Pages (from-to)	189-190
Number of pages	2
Journal	Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39830000189
Publication status	Published - 1983

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10.1039/C39830000189

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title = "The x-ray crystal structure and electronic properties of [Cu(bipy) 2(ONO)][NO3](bipy = 2,2′-bipyridyl) at 298 and 165 K, a fluxional cis-distorted octahedral CuN4O2 chromophore",

abstract = "The X-ray crystal structures of [Cu(bipy)2(ONO)][NO3] (bipy = 2,2′-bipyridyl) are reported at 298 and 165 K; significant differences occur which are consistent with a fluxional behaviour of the CuN4O2 chromophore, and enable the underlying static stereochemistry to be predicted and rationalised using the i.r. spectrum of the nitrito-group and the electronic reflectance spectrum of the CuN 4O2 chromophore.",

author = "Charles Simmons and Abraham Clearfield and William Fitzgerald and Suresh Tyagi and Brian Hathaway",

year = "1983",

doi = "10.1039/C39830000189",

language = "English",

pages = "189--190",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - The x-ray crystal structure and electronic properties of [Cu(bipy) 2(ONO)][NO3](bipy = 2,2′-bipyridyl) at 298 and 165 K, a fluxional cis-distorted octahedral CuN4O2 chromophore

AU - Simmons, Charles

AU - Clearfield, Abraham

AU - Fitzgerald, William

AU - Tyagi, Suresh

AU - Hathaway, Brian

PY - 1983

Y1 - 1983

N2 - The X-ray crystal structures of [Cu(bipy)2(ONO)][NO3] (bipy = 2,2′-bipyridyl) are reported at 298 and 165 K; significant differences occur which are consistent with a fluxional behaviour of the CuN4O2 chromophore, and enable the underlying static stereochemistry to be predicted and rationalised using the i.r. spectrum of the nitrito-group and the electronic reflectance spectrum of the CuN 4O2 chromophore.

AB - The X-ray crystal structures of [Cu(bipy)2(ONO)][NO3] (bipy = 2,2′-bipyridyl) are reported at 298 and 165 K; significant differences occur which are consistent with a fluxional behaviour of the CuN4O2 chromophore, and enable the underlying static stereochemistry to be predicted and rationalised using the i.r. spectrum of the nitrito-group and the electronic reflectance spectrum of the CuN 4O2 chromophore.

UR - https://www.scopus.com/pages/publications/37049111851

U2 - 10.1039/C39830000189

DO - 10.1039/C39830000189

M3 - Article

AN - SCOPUS:37049111851

SN - 0022-4936

SP - 189

EP - 190

JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

The x-ray crystal structure and electronic properties of [Cu(bipy) ₂(ONO)][NO₃](bipy = 2,2′-bipyridyl) at 298 and 165 K, a fluxional cis-distorted octahedral CuN₄O₂ chromophore

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