THERMODYNAMICS OF ION EXCHANGE: PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA.

Alan L. Myers; Sue Byington

doi:10.1007/978-94-009-4376-6_5

THERMODYNAMICS OF ION EXCHANGE: PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA.

Alan L. Myers
, Sue Byington

University of Pennsylvania

Research output: Chapter in Book/Report/Conference proceedings › Conference proceeding › peer-review

Abstract

One objective of this paper is to study the possibility of predicting multicomponent (N ions) exchange from (N-1) isotherms for the constituent pairs. The second objective of this paper is to describe some applications of thermodynamics to ion exchange. Most of the previous work on this subject has been devoted to the interpretation of ion exchange as a chemical reaction. This paper introduces a new approach in which ion exchange is treated as a phase equilibrium using standard procedures developed for solution thermodynamics. Surface effects are accounted for by introducing surface excess variables similar to those used to measure adsorption from liquid mixtures on solids.

Original language	English
Title of host publication	NATO ASI Series, Series E
Subtitle of host publication	Applied Sciences
Publisher	Martinus Nijhoff Publ
Pages	119-145
Number of pages	27
Edition	107
ISBN (Print)	9024732816, 9789024732814
DOIs	https://doi.org/10.1007/978-94-009-4376-6_5
Publication status	Published - 1986
Externally published	Yes

Publication series

Name	NATO ASI Series, Series E: Applied Sciences
Number	107
ISSN (Print)	0168-132X

Access to Document

10.1007/978-94-009-4376-6_5

Cite this

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title = "THERMODYNAMICS OF ION EXCHANGE: PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA.",

abstract = "One objective of this paper is to study the possibility of predicting multicomponent (N ions) exchange from (N-1) isotherms for the constituent pairs. The second objective of this paper is to describe some applications of thermodynamics to ion exchange. Most of the previous work on this subject has been devoted to the interpretation of ion exchange as a chemical reaction. This paper introduces a new approach in which ion exchange is treated as a phase equilibrium using standard procedures developed for solution thermodynamics. Surface effects are accounted for by introducing surface excess variables similar to those used to measure adsorption from liquid mixtures on solids.",

author = "Myers, \{Alan L.\} and Sue Byington",

year = "1986",

doi = "10.1007/978-94-009-4376-6\_5",

language = "English",

isbn = "9024732816",

series = "NATO ASI Series, Series E: Applied Sciences",

publisher = "Martinus Nijhoff Publ",

number = "107",

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}

THERMODYNAMICS OF ION EXCHANGE: PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA. / Myers, Alan L.; Byington, Sue.
NATO ASI Series, Series E: Applied Sciences. 107. ed. Martinus Nijhoff Publ, 1986. p. 119-145 (NATO ASI Series, Series E: Applied Sciences; No. 107).

Research output: Chapter in Book/Report/Conference proceedings › Conference proceeding › peer-review

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T2 - PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA.

AU - Myers, Alan L.

AU - Byington, Sue

PY - 1986

Y1 - 1986

N2 - One objective of this paper is to study the possibility of predicting multicomponent (N ions) exchange from (N-1) isotherms for the constituent pairs. The second objective of this paper is to describe some applications of thermodynamics to ion exchange. Most of the previous work on this subject has been devoted to the interpretation of ion exchange as a chemical reaction. This paper introduces a new approach in which ion exchange is treated as a phase equilibrium using standard procedures developed for solution thermodynamics. Surface effects are accounted for by introducing surface excess variables similar to those used to measure adsorption from liquid mixtures on solids.

AB - One objective of this paper is to study the possibility of predicting multicomponent (N ions) exchange from (N-1) isotherms for the constituent pairs. The second objective of this paper is to describe some applications of thermodynamics to ion exchange. Most of the previous work on this subject has been devoted to the interpretation of ion exchange as a chemical reaction. This paper introduces a new approach in which ion exchange is treated as a phase equilibrium using standard procedures developed for solution thermodynamics. Surface effects are accounted for by introducing surface excess variables similar to those used to measure adsorption from liquid mixtures on solids.

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DO - 10.1007/978-94-009-4376-6_5

M3 - Conference proceeding

AN - SCOPUS:0022989428

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SN - 9789024732814

T3 - NATO ASI Series, Series E: Applied Sciences

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EP - 145

BT - NATO ASI Series, Series E

PB - Martinus Nijhoff Publ

ER -

THERMODYNAMICS OF ION EXCHANGE: PREDICTION OF MULTICOMPONENT EQUILIBRIA FROM BINARY DATA.

Abstract

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