Toroid formation in polystyrene-block-poly(4-vinyl pyridine) diblock copolymers: Combined substrate and solvent control

  • Sheena M. O'Driscoll
  • , Colm T. O'Mahony
  • , Richard A. Farrell
  • , Thomas G. Fitzgerald
  • , Justin D. Holmes
  • , Michael A. Morris

Research output: Contribution to journalArticlepeer-review

Abstract

A polystyrene-block-poly(4-vinyl pyridine) diblock copolymer (PS-b-P4VP) has been used to create nanosized toroid-like structures on nitrided silicon oxide and gold substrates via simple solvent annealing of spun cast films. The significance of the role of polymer-substrate interactions in defining the morphology of the self-assembled block copolymer structure is discussed.

Original languageEnglish
Pages (from-to)65-68
Number of pages4
JournalChemical Physics Letters
Volume476
Issue number1-3
DOIs
Publication statusPublished - 7 Jul 2009

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